Calcium-catalyzed intermolecular hydrophosphination

Mark R. Crimmin; Anthony G.M. Barrett; Michael S. Hill; Peter B. Hitchcock; Panayiotis A. Procopiou

doi:10.1021/om070200k

Calcium-catalyzed intermolecular hydrophosphination

Mark R. Crimmin, Anthony G.M. Barrett, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou

Research output: Contribution to journal › Article › peer-review

161 Citations (SciVal)

Abstract

The β-diketiminato complex [{HC(C(Me)₂N-2,6- ⁱ-Pr₂C₆H₃)₂} Ca{N(SiMe₃)₂}(THF)] effects intermodular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.

Original language	English
Pages (from-to)	2953-2956
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	12
DOIs	https://doi.org/10.1021/om070200k
Publication status	Published - 4 Jun 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The β-diketiminato complex [{HC(C(Me)2N-2,6- i-Pr2C6H3)2} Ca{N(SiMe3)2}(THF)] effects intermodular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.",

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AU - Crimmin, Mark R.

AU - Barrett, Anthony G.M.

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Procopiou, Panayiotis A.

PY - 2007/6/4

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AB - The β-diketiminato complex [{HC(C(Me)2N-2,6- i-Pr2C6H3)2} Ca{N(SiMe3)2}(THF)] effects intermodular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.

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Calcium-catalyzed intermolecular hydrophosphination

Abstract

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