Calcium-catalyzed intermolecular hydrophosphination

Mark R. Crimmin, Anthony G.M. Barrett, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou

Research output: Contribution to journalArticlepeer-review

156 Citations (Scopus)

Abstract

The β-diketiminato complex [{HC(C(Me)2N-2,6- i-Pr2C6H3)2} Ca{N(SiMe3)2}(THF)] effects intermodular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.

Original languageEnglish
Pages (from-to)2953-2956
Number of pages4
JournalOrganometallics
Volume26
Issue number12
DOIs
Publication statusPublished - 4 Jun 2007

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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