Abstract
The β-diketiminato complex [{HC(C(Me)2N-2,6- i-Pr2C6H3)2} Ca{N(SiMe3)2}(THF)] effects intermodular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.
Original language | English |
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Pages (from-to) | 2953-2956 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 26 |
Issue number | 12 |
DOIs | |
Publication status | Published - 4 Jun 2007 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry