TY - JOUR
T1 - Ca2AuN
T2 - A nitride containing infinite zigzag gold chains
AU - Henry, P.F.
AU - Weller, M.T.
PY - 1998/11/2
Y1 - 1998/11/2
N2 - The high-pressure reaction of solid Ca3N2 with gold in a nitrogen atomsphere affords the ternary auride nitride Ca2AuN. In the compound, gold forms infinite, planar zigzag chains with short Au–Au bond lengths of 2.857(1) Å. The chains are sandwiched between corrugated layers of edge-sharing calcium nitride octahedra (Ca6N; see picture).
AB - The high-pressure reaction of solid Ca3N2 with gold in a nitrogen atomsphere affords the ternary auride nitride Ca2AuN. In the compound, gold forms infinite, planar zigzag chains with short Au–Au bond lengths of 2.857(1) Å. The chains are sandwiched between corrugated layers of edge-sharing calcium nitride octahedra (Ca6N; see picture).
UR - http://www.scopus.com/inward/record.url?scp=0032476784&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1002/(SICI)1521-3773(19981102)37:20<2855::AID-ANIE2855>3.0.CO;2-S
U2 - 10.1002/(SICI)1521-3773(19981102)37:20<2855::AID-ANIE2855>3.0.CO;2-S
DO - 10.1002/(SICI)1521-3773(19981102)37:20<2855::AID-ANIE2855>3.0.CO;2-S
M3 - Article
AN - SCOPUS:0032476784
SN - 1433-7851
VL - 37
SP - 2855
EP - 2857
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
IS - 20
ER -