Abstract
Alcs. have been employed as substrates for C-C bond-forming reactions which involve initial activation by the temporary removal of hydrogen to form an aldehyde. The intermediate aldehyde is converted into an alkene via a Horner-Wadsworth-Emmons reaction, nitroaldol and aldol reactions. The borrowed hydrogen is then returned to the alkene to form a C-C bond.
| Original language | English |
|---|---|
| Pages (from-to) | 116-125 |
| Number of pages | 10 |
| Journal | Organic and Biomolecular Chemistry |
| Volume | 4 |
| Issue number | 1 |
| Publication status | Published - 2006 |
Keywords
- Addition reaction
- Ketones Role
- RACT (Reactant or reagent) (iridium-catalyzed reactions for formation of C-C bonds from alcs. via intermediate conversion to aldehyde)
- Addition reaction catalysts
- RACT (Reactant or reagent) (nitro
- RCT (Reactant)
- Aldol condensation
- Horner Wadsworth Emmons reaction
- alc addn nitroalkane phosphonate ketone iridium catalyst
- Alcohols
- Aldol condensation catalysts
- iridium-catalyzed reactions for formation of C-C bonds from alcs. via intermediate conversion to aldehyde)
- Alkanes Role
- Horner Wadsworth Emmons reaction catalysts (iridium-catalyzed reactions for formation of C-C bonds from alcs. via intermediate conversion to aldehyde)