Borrowing hydrogen: A catalytic route to C-C bond formation from alcohols

Michael G Edwards; Rodolphe F R Jazzar; Belinda M Paine; Duncan J Shermer; Michael K Whittlesey; Jonathan M J Williams; Dean D Edney

Borrowing hydrogen: A catalytic route to C-C bond formation from alcohols

Michael G Edwards, Rodolphe F R Jazzar, Belinda M Paine, Duncan J Shermer, Michael K Whittlesey, Jonathan M J Williams, Dean D Edney

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

193 Citations (SciVal)

Abstract

Ruthenium complexes have been shown to perform efficient transfer hydrogenation reactions between alcs. and alkenes; in combination with an in situ Wittig reaction, indirect formation of C-C bonds has been achieved from alcs. E.g., ruthenium complex-catalyzed indirect Wittig reaction of PhCH2OH, Ph3P:CHCO2CH2Ph, and CH2:CHSiMe3 gave up to 90% PhCH2CH2CO2CH2Ph.

Original language	English
Pages (from-to)	90-91
Number of pages	2
Journal	Chemical Communications
Issue number	1
Publication status	Published - 2004

Keywords

indirect Wittig reaction ruthenium catalyst
RACT (Reactant or reagent) (transfer hydrogenation reactions between alcs. and alkenes catalyzed by ruthenium complexes)
RACT (Reactant or reagent) (hydrogen donor
Alkenes Role
Wittig reaction catalysts (indirect Wittig reaction catalyzed by ruthenium complexes)
Hydrogenation catalysts (transfer
transfer hydrogenation reactions between alcs. and alkenes catalyzed by ruthenium complexes)
Alcohols Role
transfer hydrogenation alc alkene catalyst ruthenium
Hydrogenation
Wittig reaction
RCT (Reactant)

Cite this

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title = "Borrowing hydrogen: A catalytic route to C-C bond formation from alcohols",

abstract = "Ruthenium complexes have been shown to perform efficient transfer hydrogenation reactions between alcs. and alkenes; in combination with an in situ Wittig reaction, indirect formation of C-C bonds has been achieved from alcs. E.g., ruthenium complex-catalyzed indirect Wittig reaction of PhCH2OH, Ph3P:CHCO2CH2Ph, and CH2:CHSiMe3 gave up to 90\% PhCH2CH2CO2CH2Ph.",

keywords = "indirect Wittig reaction ruthenium catalyst, RACT (Reactant or reagent) (transfer hydrogenation reactions between alcs. and alkenes catalyzed by ruthenium complexes), RACT (Reactant or reagent) (hydrogen donor, Alkenes Role, Wittig reaction catalysts (indirect Wittig reaction catalyzed by ruthenium complexes), Hydrogenation catalysts (transfer, transfer hydrogenation reactions between alcs. and alkenes catalyzed by ruthenium complexes), Alcohols Role, transfer hydrogenation alc alkene catalyst ruthenium, Hydrogenation, Wittig reaction, RCT (Reactant)",

author = "Edwards, \{Michael G\} and Jazzar, \{Rodolphe F R\} and Paine, \{Belinda M\} and Shermer, \{Duncan J\} and Whittlesey, \{Michael K\} and Williams, \{Jonathan M J\} and Edney, \{Dean D\}",

year = "2004",

language = "English",

pages = "90--91",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Borrowing hydrogen: A catalytic route to C-C bond formation from alcohols

AU - Edwards, Michael G

AU - Jazzar, Rodolphe F R

AU - Paine, Belinda M

AU - Shermer, Duncan J

AU - Whittlesey, Michael K

AU - Williams, Jonathan M J

AU - Edney, Dean D

PY - 2004

Y1 - 2004

N2 - Ruthenium complexes have been shown to perform efficient transfer hydrogenation reactions between alcs. and alkenes; in combination with an in situ Wittig reaction, indirect formation of C-C bonds has been achieved from alcs. E.g., ruthenium complex-catalyzed indirect Wittig reaction of PhCH2OH, Ph3P:CHCO2CH2Ph, and CH2:CHSiMe3 gave up to 90% PhCH2CH2CO2CH2Ph.

AB - Ruthenium complexes have been shown to perform efficient transfer hydrogenation reactions between alcs. and alkenes; in combination with an in situ Wittig reaction, indirect formation of C-C bonds has been achieved from alcs. E.g., ruthenium complex-catalyzed indirect Wittig reaction of PhCH2OH, Ph3P:CHCO2CH2Ph, and CH2:CHSiMe3 gave up to 90% PhCH2CH2CO2CH2Ph.

KW - indirect Wittig reaction ruthenium catalyst

KW - RACT (Reactant or reagent) (transfer hydrogenation reactions between alcs. and alkenes catalyzed by ruthenium complexes)

KW - RACT (Reactant or reagent) (hydrogen donor

KW - Alkenes Role

KW - Wittig reaction catalysts (indirect Wittig reaction catalyzed by ruthenium complexes)

KW - Hydrogenation catalysts (transfer

KW - transfer hydrogenation reactions between alcs. and alkenes catalyzed by ruthenium complexes)

KW - Alcohols Role

KW - transfer hydrogenation alc alkene catalyst ruthenium

KW - Hydrogenation

KW - Wittig reaction

KW - RCT (Reactant)

UR - https://www.scopus.com/pages/publications/1642580687

M3 - Article

SN - 1359-7345

SP - 90

EP - 91

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Borrowing hydrogen: A catalytic route to C-C bond formation from alcohols

Abstract

Keywords

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