Abstract
We report the synthesis and characterization of a series of arene-borazine hybrids called borazatruxenes. These molecules are BN-isosteres of truxene whereby the central benzene core has been replaced by a borazine ring. The straightforward three step synthesis, stability and their chiroptical and electronic properties recommend them as new scaffolds for BN-carbon hybrid materials. Computational studies at DFT level, closely matching the experimental data, provided insights in the electronic structure of these molecules.
| Original language | English |
|---|---|
| Pages (from-to) | 9565-9570 |
| Number of pages | 6 |
| Journal | Chemical Science |
| Volume | 10 |
| Issue number | 41 |
| Early online date | 28 Aug 2019 |
| DOIs | |
| Publication status | Published - 7 Nov 2019 |
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Borazatruxenes. / Limberti, Simone; Emmett, Liam; Trandafir, Anamaria; Kociok-Köhn, Gabriele; Pantoş, G. Dan.
In: Chemical Science, Vol. 10, No. 41, 07.11.2019, p. 9565-9570.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Borazatruxenes
AU - Limberti, Simone
AU - Emmett, Liam
AU - Trandafir, Anamaria
AU - Kociok-Köhn, Gabriele
AU - Pantoş, G. Dan
PY - 2019/11/7
Y1 - 2019/11/7
N2 - We report the synthesis and characterization of a series of arene-borazine hybrids called borazatruxenes. These molecules are BN-isosteres of truxene whereby the central benzene core has been replaced by a borazine ring. The straightforward three step synthesis, stability and their chiroptical and electronic properties recommend them as new scaffolds for BN-carbon hybrid materials. Computational studies at DFT level, closely matching the experimental data, provided insights in the electronic structure of these molecules.
AB - We report the synthesis and characterization of a series of arene-borazine hybrids called borazatruxenes. These molecules are BN-isosteres of truxene whereby the central benzene core has been replaced by a borazine ring. The straightforward three step synthesis, stability and their chiroptical and electronic properties recommend them as new scaffolds for BN-carbon hybrid materials. Computational studies at DFT level, closely matching the experimental data, provided insights in the electronic structure of these molecules.
UR - http://www.scopus.com/inward/record.url?scp=85074221667&partnerID=8YFLogxK
U2 - 10.1039/c9sc02489a
DO - 10.1039/c9sc02489a
M3 - Article
VL - 10
SP - 9565
EP - 9570
JO - Chemical Science
JF - Chemical Science
SN - 2041-6520
IS - 41
ER -