Borazatruxenes

Simone Limberti, Liam Emmett, Anamaria Trandafir, Gabriele Kociok-Köhn, G. Dan Pantoş

Research output: Contribution to journalArticlepeer-review

Abstract

We report the synthesis and characterization of a series of arene-borazine hybrids called borazatruxenes. These molecules are BN-isosteres of truxene whereby the central benzene core has been replaced by a borazine ring. The straightforward three step synthesis, stability and their chiroptical and electronic properties recommend them as new scaffolds for BN-carbon hybrid materials. Computational studies at DFT level, closely matching the experimental data, provided insights in the electronic structure of these molecules.

Original languageEnglish
Pages (from-to)9565-9570
Number of pages6
JournalChemical Science
Volume10
Issue number41
Early online date28 Aug 2019
DOIs
Publication statusPublished - 7 Nov 2019

ASJC Scopus subject areas

  • Chemistry(all)

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