[BO2]- as a Synthon for the Generation of Boron-centered Carbamate and Carboxylate Isosteres

Anne-Frédérique Pecharman; Michael Hill; Claire McMullin; Mary Mahon

doi:10.1002/anie.202005674

[BO2]- as a Synthon for the Generation of Boron-centered Carbamate and Carboxylate Isosteres

Anne-Frédérique Pecharman, Michael Hill, Claire McMullin, Mary Mahon

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Abstract

Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO2] produced by elimination of 2,3-dimethyl-2-butene from a pinacolatoboryl anion.

Original language	English
Pages (from-to)	13628-13632
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	59
Issue number	32
Early online date	13 May 2020
DOIs	https://doi.org/10.1002/anie.202005674
Publication status	Published - 3 Aug 2020

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10.1002/anie.202005674Licence: CC BY

Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M. (PI), Cresswell, A. (CoI) & McMullin, C. (Researcher)
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council

Michael Hill
- M.S.Hillbath.acuk
Person: Research & Teaching
Mary Mahon
- M.F.Mahonbath.acuk
- Department of Chemistry - Senior Lecturer
Person: Research & Teaching

Balena High Performance Computing (HPC) System
Facility/equipment: Equipment

Cite this

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title = "[BO2]- as a Synthon for the Generation of Boron-centered Carbamate and Carboxylate Isosteres",

abstract = "Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO2] produced by elimination of 2,3-dimethyl-2-butene from a pinacolatoboryl anion. ",

author = "Anne-Fr{\'e}d{\'e}rique Pecharman and Michael Hill and Claire McMullin and Mary Mahon",

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AU - Pecharman, Anne-Frédérique

AU - Hill, Michael

AU - McMullin, Claire

AU - Mahon, Mary

PY - 2020/8/3

Y1 - 2020/8/3

N2 - Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO2] produced by elimination of 2,3-dimethyl-2-butene from a pinacolatoboryl anion.

AB - Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO2] produced by elimination of 2,3-dimethyl-2-butene from a pinacolatoboryl anion.

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DO - 10.1002/anie.202005674

M3 - Article

SN - 1433-7851

VL - 59

SP - 13628

EP - 13632

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 32

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[BO2]- as a Synthon for the Generation of Boron-centered Carbamate and Carboxylate Isosteres

Abstract

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Projects

Nucleophilic alkaline earth boryls: from conception and theory to application

Profiles

Michael Hill

Mary Mahon

Equipment

Balena High Performance Computing (HPC) System

Cite this