Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

Michael S. Hill, Peter B. Hitchcock

Research output: Contribution to journalArticlepeer-review

78 Citations (Scopus)

Abstract

A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)2] to a mixture of [CH2(Ph2P≡NC6H2-Me3-2,4,6)2] and MI2(M = Ca, Sr, Ba) in THF.

Original languageEnglish
Pages (from-to)1758-1759
Number of pages2
JournalChemical Communications
Volume3
Issue number14
DOIs
Publication statusPublished - 1 Jan 2003

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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