Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

Michael S. Hill; Peter B. Hitchcock

doi:10.1039/b305430f

Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

Michael S. Hill, Peter B. Hitchcock

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80 Citations (SciVal)

Abstract

A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe₃)₂] to a mixture of [CH₂(Ph₂P≡NC₆H₂-Me₃-2,4,6)₂] and MI₂(M = Ca, Sr, Ba) in THF.

Original language	English
Pages (from-to)	1758-1759
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	14
DOIs	https://doi.org/10.1039/b305430f
Publication status	Published - 1 Jan 2003

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)2] to a mixture of [CH2(Ph2P≡NC6H2-Me3-2,4,6)2] and MI2(M = Ca, Sr, Ba) in THF.",

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N2 - A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)2] to a mixture of [CH2(Ph2P≡NC6H2-Me3-2,4,6)2] and MI2(M = Ca, Sr, Ba) in THF.

AB - A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)2] to a mixture of [CH2(Ph2P≡NC6H2-Me3-2,4,6)2] and MI2(M = Ca, Sr, Ba) in THF.

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Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

Abstract

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