Abstract
The need to mitigate the CO2 emissions deriving from the cement industry becomes imperative as the climate crisis advances. An effective strategy to achieve this is increasing the replacement level of cement clinkers by waste-derived supplementary cementitious materials (SCMs). In this study, the use of mechanochemically activated biomass ash for high-volume (up to 40%) substitution of cement is investigated. The effect of mineral carbonation treatment on the performance of the mechanochemically treated biomass ash as SCM was also examined. The results showed that the mechanochemically treated biomass ash was the most effective SCM, with the respective samples at 40% cement replacement reaching 63% of the strength at 28 days as compared to samples with 100% Portland cement, while only 17% of the strength was achieved in samples with 40% untreated biomass ash. As suggested by the isothermal calorimetry, XRD, FTIR, and TG analysis, the mechanochemical treatment enhanced the reactivity and the filler effect of the biomass ash, leading to improved mechanical performances of these mortars compared to those containing untreated biomass ash. Mineral carbonation reduced the reactivity of the mechanochemically treated biomass ash but still led to better strength performances in comparison to the untreated biomass ash.
Original language | English |
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Article number | 8357 |
Journal | Materials |
Volume | 15 |
Issue number | 23 |
DOIs | |
Publication status | Published - 24 Nov 2022 |
Bibliographical note
The authors wish to acknowledge the Transforming Foundation Industries Network+ (EPSRC grant EP/V026402/1) for funding this work.Fingerprint
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Large chamber variable pressure scanning electron microscope (SEM)
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Powder X-Ray Diffractometer (PXRD)
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STA 441 F1 Jupiter Simultaneous Thermal Analyser
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