Bio-available Solvent Cyrene: Synthesis, Derivatization, and Applications.

Research output: Contribution to journalReview article

15 Citations (Scopus)

Abstract

The development of green solvents is one of the key tenets of Green Chemistry as solvents account for the majority of waste stemming from the production of the chemicals on which we have all come to rely. An important class of solvents is the dipolar aprotics, which include N,N-dimethylformamide (DMF) and N-methyl-2-pyrrolidone (NMP). In addition to being derived from non-renewable resources, these solvents are also under increased regulatory pressures that will limit their industrial applications. This Concept concerns the bio-available solvent Cyrene (dihydrolevoglucosenone) as a potential replacement for toxic dipolar aprotic solvents. An emphasis is placed on examining the strengths and weaknesses of Cyrene as a solvent and is accomplished by looking at the synthesis, derivatization, and application in synthetic protocols of Cyrene. With respect to the Twelve Principles of Green Chemistry, this Concept describes a bio-available solvent that should have a disruptive effect on the use of traditional industrial dipolar aprotic solvents.

Original languageEnglish
Pages (from-to)3048-3055
Number of pages8
JournalChemSusChem
Volume11
Issue number18
DOIs
Publication statusPublished - 21 Sep 2018

Keywords

  • biomass conversion
  • green solvents
  • heterocycles
  • solvent effects
  • sustainable chemistry

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

Cite this

Bio-available Solvent Cyrene: Synthesis, Derivatization, and Applications. / Camp, Jason E.

In: ChemSusChem, Vol. 11, No. 18, 21.09.2018, p. 3048-3055.

Research output: Contribution to journalReview article

@article{2654092908af417b8c870fd9518e50d4,
title = "Bio-available Solvent Cyrene: Synthesis, Derivatization, and Applications.",
abstract = "The development of green solvents is one of the key tenets of Green Chemistry as solvents account for the majority of waste stemming from the production of the chemicals on which we have all come to rely. An important class of solvents is the dipolar aprotics, which include N,N-dimethylformamide (DMF) and N-methyl-2-pyrrolidone (NMP). In addition to being derived from non-renewable resources, these solvents are also under increased regulatory pressures that will limit their industrial applications. This Concept concerns the bio-available solvent Cyrene (dihydrolevoglucosenone) as a potential replacement for toxic dipolar aprotic solvents. An emphasis is placed on examining the strengths and weaknesses of Cyrene as a solvent and is accomplished by looking at the synthesis, derivatization, and application in synthetic protocols of Cyrene. With respect to the Twelve Principles of Green Chemistry, this Concept describes a bio-available solvent that should have a disruptive effect on the use of traditional industrial dipolar aprotic solvents.",
keywords = "biomass conversion, green solvents, heterocycles, solvent effects, sustainable chemistry",
author = "Camp, {Jason E.}",
note = "M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2018:1539202(Journal; General Review; Online Computer File)",
year = "2018",
month = "9",
day = "21",
doi = "10.1002/cssc.201801420",
language = "English",
volume = "11",
pages = "3048--3055",
journal = "ChemSusChem",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "18",

}

TY - JOUR

T1 - Bio-available Solvent Cyrene: Synthesis, Derivatization, and Applications.

AU - Camp, Jason E.

N1 - M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2018:1539202(Journal; General Review; Online Computer File)

PY - 2018/9/21

Y1 - 2018/9/21

N2 - The development of green solvents is one of the key tenets of Green Chemistry as solvents account for the majority of waste stemming from the production of the chemicals on which we have all come to rely. An important class of solvents is the dipolar aprotics, which include N,N-dimethylformamide (DMF) and N-methyl-2-pyrrolidone (NMP). In addition to being derived from non-renewable resources, these solvents are also under increased regulatory pressures that will limit their industrial applications. This Concept concerns the bio-available solvent Cyrene (dihydrolevoglucosenone) as a potential replacement for toxic dipolar aprotic solvents. An emphasis is placed on examining the strengths and weaknesses of Cyrene as a solvent and is accomplished by looking at the synthesis, derivatization, and application in synthetic protocols of Cyrene. With respect to the Twelve Principles of Green Chemistry, this Concept describes a bio-available solvent that should have a disruptive effect on the use of traditional industrial dipolar aprotic solvents.

AB - The development of green solvents is one of the key tenets of Green Chemistry as solvents account for the majority of waste stemming from the production of the chemicals on which we have all come to rely. An important class of solvents is the dipolar aprotics, which include N,N-dimethylformamide (DMF) and N-methyl-2-pyrrolidone (NMP). In addition to being derived from non-renewable resources, these solvents are also under increased regulatory pressures that will limit their industrial applications. This Concept concerns the bio-available solvent Cyrene (dihydrolevoglucosenone) as a potential replacement for toxic dipolar aprotic solvents. An emphasis is placed on examining the strengths and weaknesses of Cyrene as a solvent and is accomplished by looking at the synthesis, derivatization, and application in synthetic protocols of Cyrene. With respect to the Twelve Principles of Green Chemistry, this Concept describes a bio-available solvent that should have a disruptive effect on the use of traditional industrial dipolar aprotic solvents.

KW - biomass conversion

KW - green solvents

KW - heterocycles

KW - solvent effects

KW - sustainable chemistry

UR - http://www.scopus.com/inward/record.url?scp=85053028975&partnerID=8YFLogxK

U2 - 10.1002/cssc.201801420

DO - 10.1002/cssc.201801420

M3 - Review article

VL - 11

SP - 3048

EP - 3055

JO - ChemSusChem

JF - ChemSusChem

SN - 1864-5631

IS - 18

ER -