Bifunctional silyl triflates in synthesis. Part 1: Synthesis and characterization of novel alkane-,-diyl-bis(silyl triflates)

T Baker; Simon E Lewis

doi:10.1080/00397910903318724

Bifunctional silyl triflates in synthesis. Part 1: Synthesis and characterization of novel alkane-,-diyl-bis(silyl triflates)

T Baker, Simon E Lewis

Department of Chemistry

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Abstract

We report the preparation of two bifunctional silyl triflates, 1,1,4,4-tetramethyl-1,4-disila-1,4-butanediyl-bis(trifluoromethanesulfon ate) and 1,1,5,5-tetramethyl-1,5-disila-1,5-pentanediyl-bis(trifluoromethanesulfo nate). Detailed synthetic procedures and characterization data are described.

Original language	English
Pages (from-to)	2747-2752
Number of pages	6
Journal	Synthetic Communications
Volume	40
Issue number	18
DOIs	https://doi.org/10.1080/00397910903318724
Publication status	Published - Aug 2010

Keywords

organometallic reagents
silyl triflates
metathesis
arenes
protonations

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10.1080/00397910903318724

Lewis_SynthCommun_2010_40_18_2747.pdf
This is an electronic version of an article published in: Baker, T., Lewis, S. E., 2010. Bifunctional silyl triflates in synthesis. Part 1: Synthesis and characterization of novel alkane-,-diyl-bis(silyl triflates). Synthetic Communications, 40 (18), pp. 2747-2752. Synthetic Communications is available online at: http://www.informaworld.com/openurl?genre=article&issn=0039%2d7911&spage=2747
Supporting_Information.zip
This is an electronic version of an article published in: Baker, T., Lewis, S. E., 2010. Bifunctional silyl triflates in synthesis. Part 1: Synthesis and characterization of novel alkane-,-diyl-bis(silyl triflates). Synthetic Communications, 40 (18), pp. 2747-2752. Synthetic Communications is available online at: http://www.informaworld.com/openurl?genre=article&issn=0039%2d7911&spage=2747

Cite this

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title = "Bifunctional silyl triflates in synthesis. Part 1: Synthesis and characterization of novel alkane-,-diyl-bis(silyl triflates)",

abstract = "We report the preparation of two bifunctional silyl triflates, 1,1,4,4-tetramethyl-1,4-disila-1,4-butanediyl-bis(trifluoromethanesulfon ate) and 1,1,5,5-tetramethyl-1,5-disila-1,5-pentanediyl-bis(trifluoromethanesulfo nate). Detailed synthetic procedures and characterization data are described.",

keywords = "organometallic reagents, silyl triflates, metathesis, arenes, protonations",

author = "T Baker and Lewis, \{Simon E\}",

year = "2010",

month = aug,

doi = "10.1080/00397910903318724",

language = "English",

volume = "40",

pages = "2747--2752",

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AU - Baker, T

AU - Lewis, Simon E

PY - 2010/8

Y1 - 2010/8

N2 - We report the preparation of two bifunctional silyl triflates, 1,1,4,4-tetramethyl-1,4-disila-1,4-butanediyl-bis(trifluoromethanesulfon ate) and 1,1,5,5-tetramethyl-1,5-disila-1,5-pentanediyl-bis(trifluoromethanesulfo nate). Detailed synthetic procedures and characterization data are described.

AB - We report the preparation of two bifunctional silyl triflates, 1,1,4,4-tetramethyl-1,4-disila-1,4-butanediyl-bis(trifluoromethanesulfon ate) and 1,1,5,5-tetramethyl-1,5-disila-1,5-pentanediyl-bis(trifluoromethanesulfo nate). Detailed synthetic procedures and characterization data are described.

KW - organometallic reagents

KW - silyl triflates

KW - metathesis

KW - arenes

KW - protonations

UR - https://www.scopus.com/pages/publications/77955459813

UR - http://dx.doi.org/10.1080/00397910903318724

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DO - 10.1080/00397910903318724

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JO - Synthetic Communications

JF - Synthetic Communications

IS - 18

ER -

Bifunctional silyl triflates in synthesis. Part 1: Synthesis and characterization of novel alkane-,-diyl-bis(silyl triflates)

Abstract

Keywords

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