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Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.
FingerprintDive into the research topics of 'Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis'. Together they form a unique fingerprint.
- 1 Finished
23/05/11 → 31/03/15
Project: Research council