Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

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Abstract

Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.
LanguageEnglish
Pages1960-1962
Number of pages3
JournalChemical Communications
Volume49
Issue number19
DOIs
StatusPublished - 7 Mar 2013

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Catalysis
Amines
Earth (planet)
Boranes
Amides
Metals
Catalysts

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Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis. / Bellham, P.; Hill, M.S.; Kociok-Kohn, Gabriele; Liptrot, D.J.

In: Chemical Communications, Vol. 49, No. 19, 07.03.2013, p. 1960-1962.

Research output: Contribution to journalArticle

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