Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

P. Bellham; M.S. Hill; Gabriele Kociok-Kohn; D.J. Liptrot

doi:10.1039/c3cc39072a

Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

P. Bellham, M.S. Hill, Gabriele Kociok-Kohn, D.J. Liptrot

Research output: Contribution to journal › Article › peer-review

34 Citations (SciVal)

Abstract

Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.

Original language	English
Pages (from-to)	1960-1962
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	19
DOIs	https://doi.org/10.1039/c3cc39072a
Publication status	Published - 7 Mar 2013

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10.1039/c3cc39072a

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title = "Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis",

abstract = "Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.",

author = "P. Bellham and M.S. Hill and Gabriele Kociok-Kohn and D.J. Liptrot",

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T1 - Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

AU - Bellham, P.

AU - Hill, M.S.

AU - Kociok-Kohn, Gabriele

AU - Liptrot, D.J.

PY - 2013/3/7

Y1 - 2013/3/7

N2 - Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.

AB - Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.

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Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

Abstract

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

Abstract

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Projects

Group 2: Elements of 21st Century Catalysis

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

Cite this