Beryllium-induced C-N bond activation and ring opening of an N-heterocyclic carbene

Merle Arrowsmith; Michael S Hill; Gabriele Kociok-Kohn; Dugald J MacDougall; Mary F Mahon

doi:10.1002/anie.201107836

Beryllium-induced C-N bond activation and ring opening of an N-heterocyclic carbene

Merle Arrowsmith, Michael S Hill, Gabriele Kociok-Kohn, Dugald J MacDougall, Mary F Mahon

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

148 Citations (SciVal)

Abstract

Berylliant! Interaction of a well-defined adduct of MeBeH and an N-heterocyclic carbene (NHC) with PhSiH 3 results in complete rupture of the heterocycle, and activation of the NHC through effective BeH 2 insertion into a C-N bond of the heterocycle (see scheme; Ar=2,6- diisopropylphenyl, IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene).

Original language	English
Pages (from-to)	2098-2100
Number of pages	3
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	9
Early online date	20 Jan 2012
DOIs	https://doi.org/10.1002/anie.201107836
Publication status	Published - 27 Feb 2012

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10.1002/anie.201107836

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title = "Beryllium-induced C-N bond activation and ring opening of an N-heterocyclic carbene",

abstract = "Berylliant! Interaction of a well-defined adduct of MeBeH and an N-heterocyclic carbene (NHC) with PhSiH 3 results in complete rupture of the heterocycle, and activation of the NHC through effective BeH 2 insertion into a C-N bond of the heterocycle (see scheme; Ar=2,6- diisopropylphenyl, IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene).",

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year = "2012",

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AU - Arrowsmith, Merle

AU - Hill, Michael S

AU - Kociok-Kohn, Gabriele

AU - MacDougall, Dugald J

AU - Mahon, Mary F

PY - 2012/2/27

Y1 - 2012/2/27

N2 - Berylliant! Interaction of a well-defined adduct of MeBeH and an N-heterocyclic carbene (NHC) with PhSiH 3 results in complete rupture of the heterocycle, and activation of the NHC through effective BeH 2 insertion into a C-N bond of the heterocycle (see scheme; Ar=2,6- diisopropylphenyl, IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene).

AB - Berylliant! Interaction of a well-defined adduct of MeBeH and an N-heterocyclic carbene (NHC) with PhSiH 3 results in complete rupture of the heterocycle, and activation of the NHC through effective BeH 2 insertion into a C-N bond of the heterocycle (see scheme; Ar=2,6- diisopropylphenyl, IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene).

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DO - 10.1002/anie.201107836

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JF - Angewandte Chemie International Edition

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Beryllium-induced C-N bond activation and ring opening of an N-heterocyclic carbene

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Beryllium-induced C-N bond activation and ring opening of an N-heterocyclic carbene

Abstract

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Group 2: Elements of 21st Century Catalysis

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MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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