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Abstract
Reaction of BeCl2 with the dilithium diamide, [{SiNDipp}Li2] ({SiNDipp} = {CH2SiMe2NDipp}2), provides the dimeric chloroberyllate, [{SiNDippBeCl)Li]2, en route to the 2-coordinate beryllium amide, [SiNDippBe]. Lithium or sodium reduction of [SiNDippBe] in benzene, provides the relevant organoberyllate products, [{SiNDippBePh}M] (M = Li or Na), via the presumed intermediacy of transient Be(I) radicals.
Original language | English |
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Journal | Chemical communications (Cambridge, England) |
Early online date | 1 Jun 2023 |
DOIs | |
Publication status | Acceptance date - 6 Jan 2023 |
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Dive into the research topics of 'Beryllium-centred C-H Activation of Benzene'. Together they form a unique fingerprint.Projects
- 1 Finished
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Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M., Cresswell, A. & McMullin, C.
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council