Beryllium-centred C-H Activation of Benzene

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Abstract

Reaction of BeCl2 with the dilithium diamide, [{SiNDipp}Li2] ({SiNDipp} = {CH2SiMe2NDipp}2), provides the dimeric chloroberyllate, [{SiNDippBeCl)Li]2, en route to the 2-coordinate beryllium amide, [SiNDippBe]. Lithium or sodium reduction of [SiNDippBe] in benzene, provides the relevant organoberyllate products, [{SiNDippBePh}M] (M = Li or Na), via the presumed intermediacy of transient Be(I) radicals.
Original languageEnglish
Pages (from-to)1453-1456
Number of pages4
JournalChemical communications (Cambridge, England)
Volume59
Issue number11
Early online date6 Jan 2023
DOIs
Publication statusPublished - 7 Feb 2023

Bibliographical note

EPSRC - EP/R020752/1

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