Abstract
To overcome the challenges associated with poor temporal stability of perovskite solar cells, methods are required that allow for fast iteration of fabrication and characterisation, such that optimal device performance and stability may be actively pursued. Currently, establishing the causes of underperformance is both complex and time-consuming, and optimisation of device fabrication is thus inherently slow. Here, we present a means of computational device characterisation of mobile halide ion parameters from room temperature current-voltage ( J − V ) measurements only, requiring ∼2 h of computation on basic computing resources. With our approach, the physical parameters of the device may be reverse-modelled from experimental J − V measurements. In a drift-diffusion (DD) model, the set of coupled DD partial differential equations cannot be inverted explicitly, so a method for inverting the DD simulation is required. We show how Bayesian Parameter Estimation coupled with a DD perovskite solar cell model can determine the extent to which device parameters affect performance measured by J − V characteristics. Our method is demonstrated by investigating the extent to which device performance is influenced by mobile halide ions for a specific fabricated device. The ion vacancy density N 0 and diffusion coefficient DI were found to be precisely characterised for both simulated and fabricated devices. This result opens up the possibility of pinpointing origins of degradation by finding which parameters most influence device J − V curves as the cell degrades.
Original language | English |
---|---|
Article number | 015005 |
Journal | JPhys Energy |
Volume | 6 |
Issue number | 1 |
Early online date | 16 Nov 2023 |
DOIs | |
Publication status | Published - 1 Jan 2024 |
Bibliographical note
Funding Information:We thank the UK Engineering and Physical Sciences Research Council (EPSRC) for a doctoral training partnership studentship (JEC) and for a Centre for Doctoral Training in Sustainable Chemical Technologies (Grant EP/L016354/1) studentship (MVC).
Funding
We thank the UK Engineering and Physical Sciences Research Council (EPSRC) for a doctoral training partnership studentship (JEC) and for a Centre for Doctoral Training in Sustainable Chemical Technologies (Grant EP/L016354/1) studentship (MVC).
Keywords
- Bayesian parameter estimation
- drift-diffusion
- machine learning
- perovskite solar cell
ASJC Scopus subject areas
- Materials Science (miscellaneous)
- General Energy
- Materials Chemistry