Abstract
A review. This article summarizes the synthesis of azepines and cyclopentazepines by ring-closure reactions, cyclization of azaheptadienylyl anions, deprotonation, ring enlargement, thermal isomerization of azaquadricyclanes, decompn., insertion and rearrangement of arenes, that was reported in the literature from 2003-2010. Reactions of these compds. such as rearrangement, tautomerization, halogenation, alkylsulfanylation, amination, alkoxylation, and substitution of activated organooxy groups were also discussed.
| Original language | English |
|---|---|
| Title of host publication | Science of Synthesis |
| Subtitle of host publication | Knowledge Updates 2012/1 |
| Editors | J. J. Li, I. Marek, M. North, M. Oestreich, E. Schaumann, S. M. Weinreb, M. Yus |
| Place of Publication | Stuttgart, Germany |
| Publisher | Georg Thieme Verlag |
| Pages | 295-310 |
| Number of pages | 16 |
| Edition | 1 |
| ISBN (Print) | 9783131671813 |
| DOIs | |
| Publication status | Published - 2012 |
Publication series
| Name | Science of Synthesis, Knowledge Updates |
|---|---|
| Publisher | Georg Thieme Verlag |
Bibliographical note
M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved.CAPLUS AN 2015:1811910(Journal; General Review; Online Computer File)
Keywords
- review azepine cyclopentazepine prepn