Abstract
A review. This article summarizes the synthesis of azepines and cyclopentazepines by ring-closure reactions, cyclization of azaheptadienylyl anions, deprotonation, ring enlargement, thermal isomerization of azaquadricyclanes, decompn., insertion and rearrangement of arenes, that was reported in the literature from 2003-2010. Reactions of these compds. such as rearrangement, tautomerization, halogenation, alkylsulfanylation, amination, alkoxylation, and substitution of activated organooxy groups were also discussed.
Original language | English |
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Title of host publication | Science of Synthesis |
Subtitle of host publication | Knowledge Updates 2012/1 |
Editors | J. J. Li, I. Marek, M. North, M. Oestreich, E. Schaumann, S. M. Weinreb, M. Yus |
Place of Publication | Stuttgart, Germany |
Publisher | Georg Thieme Verlag |
Pages | 295-310 |
Number of pages | 16 |
Edition | 1 |
ISBN (Print) | 9783131671813 |
DOIs | |
Publication status | Published - 2012 |
Publication series
Name | Science of Synthesis, Knowledge Updates |
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Publisher | Georg Thieme Verlag |
Bibliographical note
M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved.CAPLUS AN 2015:1811910(Journal; General Review; Online Computer File)
Keywords
- review azepine cyclopentazepine prepn