Azepines, cyclopentazepines, and phosphorus analogues (update 2012)

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

A review. This article summarizes the synthesis of azepines and cyclopentazepines by ring-closure reactions, cyclization of azaheptadienylyl anions, deprotonation, ring enlargement, thermal isomerization of azaquadricyclanes, decompn., insertion and rearrangement of arenes, that was reported in the literature from 2003-2010. Reactions of these compds. such as rearrangement, tautomerization, halogenation, alkylsulfanylation, amination, alkoxylation, and substitution of activated organooxy groups were also discussed.
Original languageEnglish
Title of host publicationScience of Synthesis
Subtitle of host publicationKnowledge Updates 2012/1
EditorsJ. J. Li, I. Marek, M. North, M. Oestreich, E. Schaumann, S. M. Weinreb, M. Yus
Place of PublicationStuttgart, Germany
PublisherGeorg Thieme Verlag
Pages295-310
Number of pages16
Edition1
ISBN (Print)9783131671813
DOIs
Publication statusPublished - 2012

Publication series

NameScience of Synthesis, Knowledge Updates
PublisherGeorg Thieme Verlag

Keywords

  • review azepine cyclopentazepine prepn

Cite this

Camp, J. E. (2012). Azepines, cyclopentazepines, and phosphorus analogues (update 2012). In J. J. Li, I. Marek, M. North, M. Oestreich, E. Schaumann, S. M. Weinreb, & M. Yus (Eds.), Science of Synthesis: Knowledge Updates 2012/1 (1 ed., pp. 295-310). (Science of Synthesis, Knowledge Updates). Georg Thieme Verlag. https://doi.org/10.1055/sos-SD-117-00041