Azepines, cyclopentazepines, and phosphorus analogues (update 2012)

J. E. Camp

Research output: Chapter or section in a book/report/conference proceedingChapter or section


A review. This article summarizes the synthesis of azepines and cyclopentazepines by ring-closure reactions, cyclization of azaheptadienylyl anions, deprotonation, ring enlargement, thermal isomerization of azaquadricyclanes, decompn., insertion and rearrangement of arenes, that was reported in the literature from 2003-2010. Reactions of these compds. such as rearrangement, tautomerization, halogenation, alkylsulfanylation, amination, alkoxylation, and substitution of activated organooxy groups were also discussed.
Original languageEnglish
Title of host publicationScience of Synthesis
Subtitle of host publicationKnowledge Updates 2012/1
EditorsJ. J. Li, I. Marek, M. North, M. Oestreich, E. Schaumann, S. M. Weinreb, M. Yus
Place of PublicationStuttgart, Germany
PublisherGeorg Thieme Verlag
Number of pages16
ISBN (Print)9783131671813
Publication statusPublished - 2012

Publication series

NameScience of Synthesis, Knowledge Updates
PublisherGeorg Thieme Verlag

Bibliographical note

M1 - Copyright (C) 2018 American Chemical Society (ACS). All Rights Reserved.

CAPLUS AN 2015:1811910(Journal; General Review; Online Computer File)


  • review azepine cyclopentazepine prepn


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