Attenuated organo-magnesium activation of white phosphorus

Merle Arrowsmith; Michael S. Hill; Andrew L. Johnson; Gabriele Kociok-Kohn; Mary F. Mahon

doi:10.1002/anie.201503065

Attenuated organo-magnesium activation of white phosphorus

Merle Arrowsmith, Michael S. Hill, Andrew L. Johnson, Gabriele Kociok-Kohn, Mary F. Mahon

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47 Citations (SciVal)

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Abstract

Sequential reactions between a 2,6-di-iso-propylphenyl-substiuted -diketiminato magnesium n-butyl derivative and P4¬ allow the highly discriminating synthesis of unusual [nBu2P4]2 and [nBu2P8]2 cluster dianions.

Original language	English
Pages (from-to)	7882-7885
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	54
Issue number	27
Early online date	27 May 2015
DOIs	https://doi.org/10.1002/anie.201503065
Publication status	Published - 26 Jun 2015

Keywords

cluster compounds  magnesium  P4 activation  phosphorus  structure elucidation

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10.1002/anie.201503065Licence: CC BY

P4 Mg accepted
This is the peer reviewed version of the following article: Arrowsmith, M. , Hill, M. S., Johnson, A. L., Kociok‐Köhn, G. and Mahon, M. F. (2015), Attenuated Organomagnesium Activation of White Phosphorus. Angew. Chem. Int. Ed., 54: 7882-7885. doi:10.1002/anie.201503065, which has been published in final form at https://doi.org/10.1002/anie.201503065. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Submitted manuscript, 759 KB

Group 2: Elements of 21st Century Catalysis
Hill, M. (PI)
Engineering and Physical Sciences Research Council
23/05/11 → 31/03/15
Project: Research council

Michael Hill
- M.S.Hillbath.acuk
Person: Research & Teaching, Affiliate staff
Andrew Johnson
- A.L.Johnsonbath.acuk
Person: Research & Teaching, Core staff, Affiliate staff

MC2- Nuclear Magnetic Resonance (NMR)
Material and Chemical Characterisation (MC2)
Facility/equipment: Technology type
MC2- X-ray diffraction (XRD)
Material and Chemical Characterisation (MC2)
Facility/equipment: Technology type

Cite this

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title = "Attenuated organo-magnesium activation of white phosphorus",

abstract = "Sequential reactions between a 2,6-di-iso-propylphenyl-substiuted -diketiminato magnesium n-butyl derivative and P4¬ allow the highly discriminating synthesis of unusual [nBu2P4]2 and [nBu2P8]2 cluster dianions.",

keywords = "cluster compounds  magnesium  P4 activation  phosphorus  structure elucidation",

author = "Merle Arrowsmith and Hill, {Michael S.} and Johnson, {Andrew L.} and Gabriele Kociok-Kohn and Mahon, {Mary F.}",

year = "2015",

month = jun,

day = "26",

doi = "10.1002/anie.201503065",

language = "English",

volume = "54",

pages = "7882--7885",

journal = "Angewandte Chemie International Edition",

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AU - Arrowsmith, Merle

AU - Hill, Michael S.

AU - Johnson, Andrew L.

AU - Kociok-Kohn, Gabriele

AU - Mahon, Mary F.

PY - 2015/6/26

Y1 - 2015/6/26

N2 - Sequential reactions between a 2,6-di-iso-propylphenyl-substiuted -diketiminato magnesium n-butyl derivative and P4¬ allow the highly discriminating synthesis of unusual [nBu2P4]2 and [nBu2P8]2 cluster dianions.

AB - Sequential reactions between a 2,6-di-iso-propylphenyl-substiuted -diketiminato magnesium n-butyl derivative and P4¬ allow the highly discriminating synthesis of unusual [nBu2P4]2 and [nBu2P8]2 cluster dianions.

KW - cluster compounds  magnesium  P4 activation  phosphorus  structure elucidation

U2 - 10.1002/anie.201503065

DO - 10.1002/anie.201503065

M3 - Article

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EP - 7885

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 27

ER -

Attenuated organo-magnesium activation of white phosphorus

Abstract

Keywords

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Projects

Group 2: Elements of 21st Century Catalysis

Profiles

Michael Hill

Andrew Johnson

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

Cite this