Aromatic donor-acceptor interactions in non-polar environments

Giles M. Prentice; Sofia I. Pascu; Sorin V. Filip; Kevin R. West; Dan Pantoş

doi:10.1039/c5cc00507h

Aromatic donor-acceptor interactions in non-polar environments

Giles M. Prentice, Sofia I. Pascu, Sorin V. Filip, Kevin R. West, Dan Pantoş

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Abstract

We have evaluated the strength of aromatic donor-acceptor interactions between dialkyl naphthalenediimide and dialkoxynaphthalene in non-polar environments. ¹H NMR, UV-vis spectroscopy and isothermal titration calorimetry were used to characterise this interaction. We concluded that the strength of donor-acceptor interactions in heptane is sufficient to drive supramolecular assemblies in this and other aliphatic solvents.

Original language	English
Pages (from-to)	8265-8268
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	39
Early online date	8 Apr 2015
DOIs	https://doi.org/10.1039/c5cc00507h
Publication status	Published - 14 May 2015

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10.1039/c5cc00507h

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abstract = "We have evaluated the strength of aromatic donor-acceptor interactions between dialkyl naphthalenediimide and dialkoxynaphthalene in non-polar environments. 1H NMR, UV-vis spectroscopy and isothermal titration calorimetry were used to characterise this interaction. We concluded that the strength of donor-acceptor interactions in heptane is sufficient to drive supramolecular assemblies in this and other aliphatic solvents.",

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AU - Prentice, Giles M.

AU - Pascu, Sofia I.

AU - Filip, Sorin V.

AU - West, Kevin R.

AU - Pantoş, Dan

PY - 2015/5/14

Y1 - 2015/5/14

N2 - We have evaluated the strength of aromatic donor-acceptor interactions between dialkyl naphthalenediimide and dialkoxynaphthalene in non-polar environments. 1H NMR, UV-vis spectroscopy and isothermal titration calorimetry were used to characterise this interaction. We concluded that the strength of donor-acceptor interactions in heptane is sufficient to drive supramolecular assemblies in this and other aliphatic solvents.

AB - We have evaluated the strength of aromatic donor-acceptor interactions between dialkyl naphthalenediimide and dialkoxynaphthalene in non-polar environments. 1H NMR, UV-vis spectroscopy and isothermal titration calorimetry were used to characterise this interaction. We concluded that the strength of donor-acceptor interactions in heptane is sufficient to drive supramolecular assemblies in this and other aliphatic solvents.

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DO - 10.1039/c5cc00507h

M3 - Article

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VL - 51

SP - 8265

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Aromatic donor-acceptor interactions in non-polar environments

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Dan Pantos

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Aromatic donor-acceptor interactions in non-polar environments

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Dan Pantos

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