Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H2 binding materials on a surface

Rachel M. Hiney; Frank Marken; Paul R. Raithby; Andrew S. Weller

doi:10.1016/j.jorganchem.2009.02.003

Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H₂ binding materials on a surface

Rachel M. Hiney, Frank Marken, Paul R. Raithby, Andrew S. Weller

University of Oxford

Research output: Contribution to journal › Article › peer-review

4 Citations (SciVal)

Abstract

Water-insoluble phosphine-surface-stabilised rhodium clusters [Rh₆ (PR₃)₆ H₁₂] [BAr₄^F]₂ (R = cyclohexyl, Ar^F = (3,5-CF₃)₂C₆H₃) can be immobilised onto suitable glassy carbon, graphite, or tin-doped indium oxide (ITO) electrode surfaces. When immersed into alcohol/aqueous electrolyte media, they display stable voltammetric responses consistent with the formation of organic microdroplet

Original language	English
Pages (from-to)	2808-2813
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	17
DOIs	https://doi.org/10.1016/j.jorganchem.2009.02.003
Publication status	Published - 1 Aug 2009

Keywords

Cluster
Electrochemistry
Hydrides
Hydrogen
Redox
Rhodium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2009.02.003

Cite this

Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H₂ binding materials on a surface. / Hiney, Rachel M.; Marken, Frank ; Raithby, Paul R. et al.
In: Journal of Organometallic Chemistry, Vol. 694, No. 17, 01.08.2009, p. 2808-2813.

Research output: Contribution to journal › Article › peer-review

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abstract = "Water-insoluble phosphine-surface-stabilised rhodium clusters [Rh6 (PR3)6 H12] [BAr4F]2 (R = cyclohexyl, ArF = (3,5-CF3)2C6H3) can be immobilised onto suitable glassy carbon, graphite, or tin-doped indium oxide (ITO) electrode surfaces. When immersed into alcohol/aqueous electrolyte media, they display stable voltammetric responses consistent with the formation of organic microdroplet",

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AU - Raithby, Paul R.

AU - Weller, Andrew S.

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N2 - Water-insoluble phosphine-surface-stabilised rhodium clusters [Rh6 (PR3)6 H12] [BAr4F]2 (R = cyclohexyl, ArF = (3,5-CF3)2C6H3) can be immobilised onto suitable glassy carbon, graphite, or tin-doped indium oxide (ITO) electrode surfaces. When immersed into alcohol/aqueous electrolyte media, they display stable voltammetric responses consistent with the formation of organic microdroplet

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KW - Redox

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Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H₂ binding materials on a surface

Abstract

Keywords

ASJC Scopus subject areas

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REDOX-SWITCHABLE HYDROGEN STORAGE MATERIALS: HYDROGEN BURST DEVICE PROTOTYPES

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Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H2 binding materials on a surface

Abstract

Keywords

ASJC Scopus subject areas

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Fingerprint

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REDOX-SWITCHABLE HYDROGEN STORAGE MATERIALS: HYDROGEN BURST DEVICE PROTOTYPES

Cite this

Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H₂ binding materials on a surface