An unusual Co2-containing anion: Synthesis and structure of [(OxS)Ca·4HMPA]+·[(OxS)Co·μ-(OxS) 3·CoCl]- [OxS- = C6H 4O·(C=S)=N-; HMPA = O=P(NMe2) 3]

Matthew G. Davidson; Malcolm Gerloch; S. Clare Llewellyn; Paul R. Raithby; Ronald Snaith

doi:10.1039/C39930001363

An unusual Co₂-containing anion: Synthesis and structure of [(OxS)Ca·4HMPA]⁺·[(OxS)Co·μ-(OxS) ₃·CoCl]^- [OxS^- = C₆H ₄O·(C=S)=N^-; HMPA = O=P(NMe₂) ₃]

Matthew G. Davidson
, Malcolm Gerloch
, S. Clare Llewellyn
, Paul R. Raithby
, Ronald Snaith

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Solid CoCl₂ dissolves in a toluene solution of (OxS)₂ Ca·2HMPA to give [(OxS)Ca·4HMPA]⁺·[(OxS) Co·μ-(OxS)₃·CoCl]^-, 1, the anion structure consists of two Co₂⁺ centres linked by three symmetrically bridging OxS^- ligands such that one Co²⁺ (bonded through S to a terminal OxS^-) has a tetrahedral coordination sphere of four S atoms whilst the other (bonded to a terminal Cl^-) has a tetrahedral coordination sphere of three N and one Cl atoms.

Original language	English
Pages (from-to)	1363-1364
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39930001363
Publication status	Published - 1993

ASJC Scopus subject areas

Molecular Medicine

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An unusual Co₂-containing anion: Synthesis and structure of [(OxS)Ca·4HMPA]⁺·[(OxS)Co·μ-(OxS) ₃·CoCl]^- [OxS^- = C₆H ₄O·(C=S)=N^-; HMPA = O=P(NMe₂) ₃]. / Davidson, Matthew G.; Gerloch, Malcolm; Llewellyn, S. Clare et al.
In: Journal of the Chemical Society, Chemical Communications, No. 17, 1993, p. 1363-1364.

Research output: Contribution to journal › Article › peer-review

@article{f43f926c80954044bb03118f4304f56a,

title = "An unusual Co2-containing anion: Synthesis and structure of [(OxS)Ca·4HMPA]+·[(OxS)Co·μ-(OxS) 3·CoCl]- [OxS- = C6H 4O·(C=S)=N-; HMPA = O=P(NMe2) 3]",

abstract = "Solid CoCl2 dissolves in a toluene solution of (OxS)2 Ca·2HMPA to give [(OxS)Ca·4HMPA]+·[(OxS) Co·μ-(OxS)3·CoCl]-, 1, the anion structure consists of two Co2+ centres linked by three symmetrically bridging OxS- ligands such that one Co2+ (bonded through S to a terminal OxS-) has a tetrahedral coordination sphere of four S atoms whilst the other (bonded to a terminal Cl-) has a tetrahedral coordination sphere of three N and one Cl atoms.",

author = "Davidson, \{Matthew G.\} and Malcolm Gerloch and Llewellyn, \{S. Clare\} and Raithby, \{Paul R.\} and Ronald Snaith",

year = "1993",

doi = "10.1039/C39930001363",

language = "English",

pages = "1363--1364",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "17",

}

TY - JOUR

T1 - An unusual Co2-containing anion

T2 - Synthesis and structure of [(OxS)Ca·4HMPA]+·[(OxS)Co·μ-(OxS) 3·CoCl]- [OxS- = C6H 4O·(C=S)=N-; HMPA = O=P(NMe2) 3]

AU - Davidson, Matthew G.

AU - Gerloch, Malcolm

AU - Llewellyn, S. Clare

AU - Raithby, Paul R.

AU - Snaith, Ronald

PY - 1993

Y1 - 1993

N2 - Solid CoCl2 dissolves in a toluene solution of (OxS)2 Ca·2HMPA to give [(OxS)Ca·4HMPA]+·[(OxS) Co·μ-(OxS)3·CoCl]-, 1, the anion structure consists of two Co2+ centres linked by three symmetrically bridging OxS- ligands such that one Co2+ (bonded through S to a terminal OxS-) has a tetrahedral coordination sphere of four S atoms whilst the other (bonded to a terminal Cl-) has a tetrahedral coordination sphere of three N and one Cl atoms.

AB - Solid CoCl2 dissolves in a toluene solution of (OxS)2 Ca·2HMPA to give [(OxS)Ca·4HMPA]+·[(OxS) Co·μ-(OxS)3·CoCl]-, 1, the anion structure consists of two Co2+ centres linked by three symmetrically bridging OxS- ligands such that one Co2+ (bonded through S to a terminal OxS-) has a tetrahedral coordination sphere of four S atoms whilst the other (bonded to a terminal Cl-) has a tetrahedral coordination sphere of three N and one Cl atoms.

UR - https://www.scopus.com/pages/publications/37049073713

U2 - 10.1039/C39930001363

DO - 10.1039/C39930001363

M3 - Article

AN - SCOPUS:37049073713

SN - 0022-4936

SP - 1363

EP - 1364

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

An unusual Co₂-containing anion: Synthesis and structure of [(OxS)Ca·4HMPA]⁺·[(OxS)Co·μ-(OxS) ₃·CoCl]^- [OxS^- = C₆H ₄O·(C=S)=N^-; HMPA = O=P(NMe₂) ₃]

Abstract

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