TY - JOUR
T1 - An unusual Co2-containing anion
T2 - Synthesis and structure of [(OxS)Ca·4HMPA]+·[(OxS)Co·μ-(OxS) 3·CoCl]- [OxS- = C6H 4O·(C=S)=N-; HMPA = O=P(NMe2) 3]
AU - Davidson, Matthew G.
AU - Gerloch, Malcolm
AU - Llewellyn, S. Clare
AU - Raithby, Paul R.
AU - Snaith, Ronald
PY - 1993
Y1 - 1993
N2 - Solid CoCl2 dissolves in a toluene solution of (OxS)2 Ca·2HMPA to give [(OxS)Ca·4HMPA]+·[(OxS) Co·μ-(OxS)3·CoCl]-, 1, the anion structure consists of two Co2+ centres linked by three symmetrically bridging OxS- ligands such that one Co2+ (bonded through S to a terminal OxS-) has a tetrahedral coordination sphere of four S atoms whilst the other (bonded to a terminal Cl-) has a tetrahedral coordination sphere of three N and one Cl atoms.
AB - Solid CoCl2 dissolves in a toluene solution of (OxS)2 Ca·2HMPA to give [(OxS)Ca·4HMPA]+·[(OxS) Co·μ-(OxS)3·CoCl]-, 1, the anion structure consists of two Co2+ centres linked by three symmetrically bridging OxS- ligands such that one Co2+ (bonded through S to a terminal OxS-) has a tetrahedral coordination sphere of four S atoms whilst the other (bonded to a terminal Cl-) has a tetrahedral coordination sphere of three N and one Cl atoms.
UR - http://www.scopus.com/inward/record.url?scp=37049073713&partnerID=8YFLogxK
U2 - 10.1039/C39930001363
DO - 10.1039/C39930001363
M3 - Article
AN - SCOPUS:37049073713
SN - 0022-4936
SP - 1363
EP - 1364
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 17
ER -