An enantioselective fluorescent sensor for sugar acids

J Z Zhao; M G Davidson; M F Mahon; G Kociok-Kohn; T D James

doi:10.1021/ja046289s

An enantioselective fluorescent sensor for sugar acids

J Z Zhao, M G Davidson, M F Mahon, G Kociok-Kohn, T D James

Department of Chemistry

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186 Citations (SciVal)

Abstract

Chiral fluorescent boronic acid 1 was found to be a highly enantioselective, chemoselective, and sensitive sensor for sugar acids, such as tartaric acid. Enantioselectivities (K-R/K-S) of up to 550:1, chemoselectivity up to 11000:1, and sensitivities in the micromolar range with sensor 1 were observed. Single-crystal X-ray analysis was used to confirm the structure of the fluorescent species.

Original language	English
Pages (from-to)	16179-16186
Number of pages	8
Journal	Journal of the American Chemical Society
Volume	126
Issue number	49
DOIs	https://doi.org/10.1021/ja046289s
Publication status	Published - 2004

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ID number: ISI:000225697000053

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10.1021/ja046289s

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abstract = "Chiral fluorescent boronic acid 1 was found to be a highly enantioselective, chemoselective, and sensitive sensor for sugar acids, such as tartaric acid. Enantioselectivities (K-R/K-S) of up to 550:1, chemoselectivity up to 11000:1, and sensitivities in the micromolar range with sensor 1 were observed. Single-crystal X-ray analysis was used to confirm the structure of the fluorescent species.",

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AU - Mahon, M F

AU - Kociok-Kohn, G

AU - James, T D

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AB - Chiral fluorescent boronic acid 1 was found to be a highly enantioselective, chemoselective, and sensitive sensor for sugar acids, such as tartaric acid. Enantioselectivities (K-R/K-S) of up to 550:1, chemoselectivity up to 11000:1, and sensitivities in the micromolar range with sensor 1 were observed. Single-crystal X-ray analysis was used to confirm the structure of the fluorescent species.

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M3 - Article

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 49

ER -

An enantioselective fluorescent sensor for sugar acids

Abstract

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