An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

Philip Axe; S D Bull; M G Davidson; M D Jones; D E J E Robinson; W L Mitchell; J E Warren

doi:10.1039/b918141p

An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

Philip Axe, S D Bull, M G Davidson, M D Jones, D E J E Robinson, W L Mitchell, J E Warren

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

Abstract

A chiral pseudo-C-3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

Original language	English
Pages (from-to)	10169-10171
Number of pages	3
Journal	Dalton Transactions
Volume	2009
Issue number	46
DOIs	https://doi.org/10.1039/b918141p
Publication status	Published - 2009

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title = "An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions",

abstract = "A chiral pseudo-C-3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.",

author = "Philip Axe and Bull, {S D} and Davidson, {M G} and Jones, {M D} and Robinson, {D E J E} and Mitchell, {W L} and Warren, {J E}",

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AU - Axe, Philip

AU - Bull, S D

AU - Davidson, M G

AU - Jones, M D

AU - Robinson, D E J E

AU - Mitchell, W L

AU - Warren, J E

PY - 2009

Y1 - 2009

N2 - A chiral pseudo-C-3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

AB - A chiral pseudo-C-3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

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UR - http://dx.doi.org/10.1039/b918141p

U2 - 10.1039/b918141p

DO - 10.1039/b918141p

M3 - Article

SN - 1477-9226

VL - 2009

SP - 10169

EP - 10171

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -

An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

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