An air stable moisture resistant titanium triflate complex as a Lewis acid catalyst for C-C bond forming reactions

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Abstract

An air and moisture stable C-3-symmetric titanium(IV) triflate, supported by a tripodal amine-(tris-phenolate) ligand, has been synthesized and characterized by X-ray crystallography and shown to be a good Lewis acid catalyst for a range of aza-Diets-Alder, Diels-Alder, syn aldol, allylation, and alkylation reactions.
Original languageEnglish
Pages (from-to)612-620
Number of pages9
JournalChemistry - An Asian Journal
Volume5
Issue number3
DOIs
Publication statusPublished - 2010

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Allylation
Lewis Acids
X ray crystallography
Alkylation
Nutrition
Titanium
Amines
Moisture
Ligands
Catalysts
Air
3-hydroxybutanal

Cite this

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abstract = "An air and moisture stable C-3-symmetric titanium(IV) triflate, supported by a tripodal amine-(tris-phenolate) ligand, has been synthesized and characterized by X-ray crystallography and shown to be a good Lewis acid catalyst for a range of aza-Diets-Alder, Diels-Alder, syn aldol, allylation, and alkylation reactions.",
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AU - Robinson, D E J E

PY - 2010

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AB - An air and moisture stable C-3-symmetric titanium(IV) triflate, supported by a tripodal amine-(tris-phenolate) ligand, has been synthesized and characterized by X-ray crystallography and shown to be a good Lewis acid catalyst for a range of aza-Diets-Alder, Diels-Alder, syn aldol, allylation, and alkylation reactions.

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