An air-stable [Cu(NHC)(OR)] (R = C(H)(CF3)2) complex for C-H, N-H and S-H bond activation

Sylwia Ostrowska; Pierre Arnaut; David J. Liptrot; Catherine S. J. Cazin; Steven P. Nolan

doi:10.1039/d3cc02318d

An air-stable [Cu(NHC)(OR)] (R = C(H)(CF₃)₂) complex for C-H, N-H and S-H bond activation

Sylwia Ostrowska, Pierre Arnaut, David J. Liptrot, Catherine S. J. Cazin, Steven P. Nolan

Ghent University

Research output: Contribution to journal › Article › peer-review

3 Citations (SciVal)

Abstract

The synthesis, isolation and full characterisation of a [Cu(IPr)(OC(H)(CF₃)₂)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) complex are reported. This new Cu(i) complex is a versatile synthon and can activate numerous X-H bonds including C-H, N-H and S-H bonds. [Cu(IPr)(OC(H)(CF₃)₂)] was investigated as a pre-catalyst in several catalytic reactions.

Original language	English
Pages (from-to)	9126-9129
Journal	Chemical Communications
Volume	59
Issue number	59
Early online date	28 Jun 2023
DOIs	https://doi.org/10.1039/d3cc02318d
Publication status	Published - 28 Jul 2023

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc02318d

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title = "An air-stable [Cu(NHC)(OR)] (R = C(H)(CF3)2) complex for C-H, N-H and S-H bond activation",

abstract = "The synthesis, isolation and full characterisation of a [Cu(IPr)(OC(H)(CF3)2)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) complex are reported. This new Cu(i) complex is a versatile synthon and can activate numerous X-H bonds including C-H, N-H and S-H bonds. [Cu(IPr)(OC(H)(CF3)2)] was investigated as a pre-catalyst in several catalytic reactions.",

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T1 - An air-stable [Cu(NHC)(OR)] (R = C(H)(CF3)2) complex for C-H, N-H and S-H bond activation

AU - Ostrowska, Sylwia

AU - Arnaut, Pierre

AU - Liptrot, David J.

AU - Cazin, Catherine S. J.

AU - Nolan, Steven P.

PY - 2023/7/28

Y1 - 2023/7/28

N2 - The synthesis, isolation and full characterisation of a [Cu(IPr)(OC(H)(CF3)2)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) complex are reported. This new Cu(i) complex is a versatile synthon and can activate numerous X-H bonds including C-H, N-H and S-H bonds. [Cu(IPr)(OC(H)(CF3)2)] was investigated as a pre-catalyst in several catalytic reactions.

AB - The synthesis, isolation and full characterisation of a [Cu(IPr)(OC(H)(CF3)2)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) complex are reported. This new Cu(i) complex is a versatile synthon and can activate numerous X-H bonds including C-H, N-H and S-H bonds. [Cu(IPr)(OC(H)(CF3)2)] was investigated as a pre-catalyst in several catalytic reactions.

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U2 - 10.1039/d3cc02318d

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SN - 1359-7345

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SP - 9126

EP - 9129

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

An air-stable [Cu(NHC)(OR)] (R = C(H)(CF₃)₂) complex for C-H, N-H and S-H bond activation

Abstract

ASJC Scopus subject areas

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