Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride

Ella F. Clark; Estelle Dunstan; Gabriele Kociok-Köhn; Antoine Buchard

doi:10.1039/D4CC03947E

Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride

Ella F. Clark, Estelle Dunstan, Gabriele Kociok-Köhn, Antoine Buchard

University of York

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Abstract

The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation of cyclohexene oxide and phthalic anhydride without the need for a co-initiator.

Original language	English
Pages (from-to)	13067-13070
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	89
Early online date	22 Oct 2024
DOIs	https://doi.org/10.1039/D4CC03947E
Publication status	Published - 18 Nov 2024

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The data supporting this article have been included as part of the ESI.

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10.1039/D4CC03947ELicence: CC BY

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title = "Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride",

abstract = "The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation of cyclohexene oxide and phthalic anhydride without the need for a co-initiator.",

author = "Clark, {Ella F.} and Estelle Dunstan and Gabriele Kociok-K{\"o}hn and Antoine Buchard",

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AU - Clark, Ella F.

AU - Dunstan, Estelle

AU - Kociok-Köhn, Gabriele

AU - Buchard, Antoine

PY - 2024/11/18

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N2 - The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation of cyclohexene oxide and phthalic anhydride without the need for a co-initiator.

AB - The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation of cyclohexene oxide and phthalic anhydride without the need for a co-initiator.

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U2 - 10.1039/D4CC03947E

DO - 10.1039/D4CC03947E

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Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride

Abstract

Data Availability Statement

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