Amine-triggered molecular capsules using dynamic boronate esterification

K Kataoka; S Okuyama; T Minami; Tony D James; Y Kubo

doi:10.1039/b900102f

Amine-triggered molecular capsules using dynamic boronate esterification

K Kataoka, S Okuyama, T Minami, Tony D James, Y Kubo

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Citations (SciVal)

Abstract

Boron-contained molecular capsules triggered by amines are described for the first time; when Et3N was employed as a chemical stimulus the Lewis acid Et3NH+, produced by solvolysis reaction on the boron, was found to be encapsulated in the internal cavity, whereas use of (Bu3N)-Bu-n led to the related dynamic capsule capable of accommodating several guest species including Cs+.

Original language	English
Pages (from-to)	1682-1684
Number of pages	3
Journal	Chemical Communications
Volume	13
DOIs	https://doi.org/10.1039/b900102f
Publication status	Published - 2009

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title = "Amine-triggered molecular capsules using dynamic boronate esterification",

abstract = "Boron-contained molecular capsules triggered by amines are described for the first time; when Et3N was employed as a chemical stimulus the Lewis acid Et3NH+, produced by solvolysis reaction on the boron, was found to be encapsulated in the internal cavity, whereas use of (Bu3N)-Bu-n led to the related dynamic capsule capable of accommodating several guest species including Cs+.",

author = "K Kataoka and S Okuyama and T Minami and James, {Tony D} and Y Kubo",

year = "2009",

doi = "10.1039/b900102f",

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T1 - Amine-triggered molecular capsules using dynamic boronate esterification

AU - Kataoka, K

AU - Okuyama, S

AU - Minami, T

AU - James, Tony D

AU - Kubo, Y

PY - 2009

Y1 - 2009

N2 - Boron-contained molecular capsules triggered by amines are described for the first time; when Et3N was employed as a chemical stimulus the Lewis acid Et3NH+, produced by solvolysis reaction on the boron, was found to be encapsulated in the internal cavity, whereas use of (Bu3N)-Bu-n led to the related dynamic capsule capable of accommodating several guest species including Cs+.

AB - Boron-contained molecular capsules triggered by amines are described for the first time; when Et3N was employed as a chemical stimulus the Lewis acid Et3NH+, produced by solvolysis reaction on the boron, was found to be encapsulated in the internal cavity, whereas use of (Bu3N)-Bu-n led to the related dynamic capsule capable of accommodating several guest species including Cs+.

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UR - http://dx.doi.org/10.1039/b900102f

U2 - 10.1039/b900102f

DO - 10.1039/b900102f

M3 - Article

SN - 1359-7345

VL - 13

SP - 1682

EP - 1684

JO - Chemical Communications

JF - Chemical Communications

ER -

Amine-triggered molecular capsules using dynamic boronate esterification

Abstract

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