Projects per year
Copper‐alumanyl complexes, [LCu‐Al(SiN Dipp )], where L = carbene = NHC iPr (N,Nʹ‐di‐isopropyl‐4,5‐dimethyl‐2‐ylidene) and Me2 CAAC (1‐(2,6‐di‐isopropylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene) and featuring unsupported Al‐Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO 2 implies an ambiphilicity in the Cu‐Al interaction that is dependent on the identity of the carbene co‐ligand.
|Journal||Angewandte Chemie-International Edition|
|Early online date||25 Apr 2021|
|Publication status||Published - 21 Jun 2021|
- 2 Finished
Ryan Schwamm- 1851 Fellowship - Activation of Nitrogen using Alkaline Earth Metals
Schwamm, R. & Hill, M.
Royal Commission for the Exhibition of 1851
5/11/18 → 4/11/21
Project: UK charity
Nucleophilic alkaline earth boryls: from conception and theory to application
Hill, M., Cresswell, A. & McMullin, C.
Engineering and Physical Sciences Research Council
1/05/18 → 31/07/22
Project: Research council