Aluminium-Catalysed Isocyanate Trimerization, Enhanced by Exploiting a Dynamic Coordination Sphere

Mohammed Bahili, Emily Stokes, Robert Amesbury, Darren Ould, Bashar Christo, Rhian Horne, Benson Kariuki, Jack Stewart, Rebekah Taylor, Andrew Williams, Matthew Jones, Kenneth Harris, Benjamin Ward

Research output: Contribution to journalArticle

Abstract

Main-group metals are inherently labile, hindering their use in catalysis. We exploit this lability in the synthesis of isocyanurates. For the first time we report a highly active catalyst that trimerizes alkyl, allyl and aryl isocyanates, and di-isocyanates, with low catalyst loadings under mild conditions, using a hemi-labile aluminium-pyridyl-bis(iminophenolate) complex.

Original languageEnglish
Pages (from-to)7679-7682
Number of pages4
JournalChemical communications (Cambridge, England)
Volume55
Issue number53
Early online date17 Jun 2019
DOIs
Publication statusPublished - 7 Jul 2019

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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