Alkaline- earth-promoted CO homologation and reductive catalysis

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Abstract

Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.
LanguageEnglish
Pages10009-10011
JournalAngewandte Chemie-International Edition
Volume54
Issue number34
Early online date24 Jul 2015
DOIs
StatusPublished - 17 Aug 2015

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Carbon Monoxide
Catalysis
Magnesium

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Alkaline- earth-promoted CO homologation and reductive catalysis. / Anker, Mathew D.; Hill, Michael S.; Lowe, John P.; Mahon, Mary F.

In: Angewandte Chemie-International Edition, Vol. 54, No. 34, 17.08.2015, p. 10009-10011.

Research output: Contribution to journalArticle

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