Alkaline- earth-promoted CO homologation and reductive catalysis

Mathew D. Anker; Michael S. Hill; John P. Lowe; Mary F. Mahon

doi:10.1002/anie.201505851

Alkaline- earth-promoted CO homologation and reductive catalysis

Mathew D. Anker, Michael S. Hill, John P. Lowe, Mary F. Mahon

Research output: Contribution to journal › Article › peer-review

69 Citations (SciVal)

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Abstract

Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.

Original language	English
Pages (from-to)	10009-10011
Number of pages	3
Journal	Angewandte Chemie International Edition
Volume	54
Issue number	34
Early online date	24 Jul 2015
DOIs	https://doi.org/10.1002/anie.201505851
Publication status	Published - 10 Aug 2015

Keywords

Carbon monoxide
Catalysis
Fischer-Tropsch synthesis
Magnesium
Reduction

Access to Document

10.1002/anie.201505851Licence: CC BY

Group 2: Elements of 21st Century Catalysis
Hill, M. (PI)
Engineering and Physical Sciences Research Council
23/05/11 → 31/03/15
Project: Research council

Michael Hill
- M.S.Hillbath.acuk
Person: Research & Teaching

MC2- Nuclear Magnetic Resonance (NMR)
Material and Chemical Characterisation (MC2)
Facility/equipment: Technology type
MC2- X-ray diffraction (XRD)
Material and Chemical Characterisation (MC2)
Facility/equipment: Technology type

Cite this

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title = "Alkaline- earth-promoted CO homologation and reductive catalysis",

abstract = "Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond. ",

keywords = "Carbon monoxide, Catalysis, Fischer-Tropsch synthesis, Magnesium, Reduction",

author = "Anker, {Mathew D.} and Hill, {Michael S.} and Lowe, {John P.} and Mahon, {Mary F.}",

year = "2015",

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doi = "10.1002/anie.201505851",

language = "English",

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pages = "10009--10011",

journal = "Angewandte Chemie International Edition",

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T1 - Alkaline- earth-promoted CO homologation and reductive catalysis

AU - Anker, Mathew D.

AU - Hill, Michael S.

AU - Lowe, John P.

AU - Mahon, Mary F.

PY - 2015/8/10

Y1 - 2015/8/10

N2 - Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.

AB - Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.

KW - Carbon monoxide

KW - Catalysis

KW - Fischer-Tropsch synthesis

KW - Magnesium

KW - Reduction

U2 - 10.1002/anie.201505851

DO - 10.1002/anie.201505851

M3 - Article

SN - 1433-7851

VL - 54

SP - 10009

EP - 10011

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 34

ER -

Alkaline- earth-promoted CO homologation and reductive catalysis

Abstract

Keywords

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Projects

Group 2: Elements of 21st Century Catalysis

Profiles

Michael Hill

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

Cite this