Alkaline- earth-promoted CO homologation and reductive catalysis

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Abstract

Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.
Original languageEnglish
Pages (from-to)10009-10011
Number of pages3
JournalAngewandte Chemie-International Edition
Volume54
Issue number34
Early online date24 Jul 2015
DOIs
Publication statusPublished - 10 Aug 2015

Keywords

  • Carbon monoxide
  • Catalysis
  • Fischer-Tropsch synthesis
  • Magnesium
  • Reduction

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