Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

Merle Arrowsmith; William M S Shepherd; Michael S. Hill; Gabriele Kociok-Köhn

doi:10.1039/c4cc05223d

Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

Merle Arrowsmith, William M S Shepherd, Michael S. Hill, Gabriele Kociok-Köhn

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Abstract

A variety of functionalised imidazolidin-2-ones may be synthesised under very mild reaction conditions using non-toxic and cost-effective alkaline earth bis(amide) pre-catalysts in a 100% atom-efficient, intermolecular one-pot assembly from inexpensive alkyne and cumulene reagents. This journal is

Original language	English
Pages (from-to)	12676-12679
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	84
Early online date	5 Sept 2014
DOIs	https://doi.org/10.1039/c4cc05223d
Publication status	Published - 28 Oct 2014

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10.1039/c4cc05223d

Atom-efficient imidazolinones_CC_revisedAccepted author manuscript, 848 KB

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Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

Abstract

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Alkaline earth catalysis for the 100% atom-efficient three component assembly of imidazolidin-2-ones

Abstract

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Projects

Group 2: Elements of 21st Century Catalysis

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

Cite this