Alkali metal-mediated Dehydrocoupling of Me2NH.BH3

Peter Bellham; Michael S. Hill; Gabriele Kociok-Kohn

doi:10.1039/C5DT00178A

Alkali metal-mediated Dehydrocoupling of Me₂NH.BH₃

Peter Bellham, Michael S. Hill, Gabriele Kociok-Kohn

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Abstract

Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3via the formation of intermediates containing [H3BNMe2BH2Me2N]− anions.

Original language	English
Pages (from-to)	12078-12081
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	27
Early online date	13 Mar 2015
DOIs	https://doi.org/10.1039/C5DT00178A
Publication status	Published - 21 Jul 2015

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10.1039/C5DT00178A

galleyAccepted author manuscript, 332 KBLicence: CC BY-ND

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title = "Alkali metal-mediated Dehydrocoupling of Me2NH.BH3",

abstract = "Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3via the formation of intermediates containing [H3BNMe2BH2Me2N]− anions.",

author = "Peter Bellham and Hill, {Michael S.} and Gabriele Kociok-Kohn",

year = "2015",

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language = "English",

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publisher = "Royal Society of Chemistry",

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T1 - Alkali metal-mediated Dehydrocoupling of Me2NH.BH3

AU - Bellham, Peter

AU - Hill, Michael S.

AU - Kociok-Kohn, Gabriele

PY - 2015/7/21

Y1 - 2015/7/21

N2 - Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3via the formation of intermediates containing [H3BNMe2BH2Me2N]− anions.

AB - Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3via the formation of intermediates containing [H3BNMe2BH2Me2N]− anions.

UR - http://dx.doi.org/10.1039/C5DT00178A

U2 - 10.1039/C5DT00178A

DO - 10.1039/C5DT00178A

M3 - Article

SN - 1477-9226

VL - 44

SP - 12078

EP - 12081

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

Alkali metal-mediated Dehydrocoupling of Me₂NH.BH₃

Abstract

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Group 2: Elements of 21st Century Catalysis

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Alkali metal-mediated Dehydrocoupling of Me2NH.BH3

Abstract

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Group 2: Elements of 21st Century Catalysis

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MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

Cite this

Alkali metal-mediated Dehydrocoupling of Me₂NH.BH₃