Air-stable titanium alkoxide based metal-organic framework as an initiator for ring-opening polymerization of cyclic esters

C J Chuck; M G Davidson; M D Jones; G Kociok-Kohn; M D Lunn; S Wu

doi:10.1021/ic060969+

Air-stable titanium alkoxide based metal-organic framework as an initiator for ring-opening polymerization of cyclic esters

C J Chuck, M G Davidson, M D Jones, G Kociok-Kohn, M D Lunn, S Wu

Research output: Contribution to journal › Article › peer-review

92 Citations (SciVal)

Abstract

An air-stable titanium-organic framework, prepared from Ti((OPr)-Pr-i)(4) and 1,4-butanediol, has been characterized via single-crystal X- ray diffraction, revealing a unique supramolecular structure. Its functionality as a highly active initiator for the ring-opening polymerization of cyclic esters is demonstrated. A discrete titanium trimer containing the related ligand (2R,3R)-2,3-butanediol has also been prepared, and it shows analogous activity as a polymerization initiator.

Original language	English
Pages (from-to)	6595-6597
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	17
DOIs	https://doi.org/10.1021/ic060969+
Publication status	Published - 2006

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ID number: ISI:000239723300014

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abstract = "An air-stable titanium-organic framework, prepared from Ti((OPr)-Pr-i)(4) and 1,4-butanediol, has been characterized via single-crystal X- ray diffraction, revealing a unique supramolecular structure. Its functionality as a highly active initiator for the ring-opening polymerization of cyclic esters is demonstrated. A discrete titanium trimer containing the related ligand (2R,3R)-2,3-butanediol has also been prepared, and it shows analogous activity as a polymerization initiator.",

author = "Chuck, {C J} and Davidson, {M G} and Jones, {M D} and G Kociok-Kohn and Lunn, {M D} and S Wu",

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AU - Chuck, C J

AU - Davidson, M G

AU - Jones, M D

AU - Kociok-Kohn, G

AU - Lunn, M D

AU - Wu, S

N1 - ID number: ISI:000239723300014

PY - 2006

Y1 - 2006

N2 - An air-stable titanium-organic framework, prepared from Ti((OPr)-Pr-i)(4) and 1,4-butanediol, has been characterized via single-crystal X- ray diffraction, revealing a unique supramolecular structure. Its functionality as a highly active initiator for the ring-opening polymerization of cyclic esters is demonstrated. A discrete titanium trimer containing the related ligand (2R,3R)-2,3-butanediol has also been prepared, and it shows analogous activity as a polymerization initiator.

AB - An air-stable titanium-organic framework, prepared from Ti((OPr)-Pr-i)(4) and 1,4-butanediol, has been characterized via single-crystal X- ray diffraction, revealing a unique supramolecular structure. Its functionality as a highly active initiator for the ring-opening polymerization of cyclic esters is demonstrated. A discrete titanium trimer containing the related ligand (2R,3R)-2,3-butanediol has also been prepared, and it shows analogous activity as a polymerization initiator.

U2 - 10.1021/ic060969+

DO - 10.1021/ic060969+

M3 - Article

SN - 0020-1669

VL - 45

SP - 6595

EP - 6597

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Air-stable titanium alkoxide based metal-organic framework as an initiator for ring-opening polymerization of cyclic esters

Abstract

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