Acyclic pyrrole-based anion receptors: design, synthesis, and anion-binding properties

Jonathan L. Sessler, Natalie M. Barkey, G. Dan Pantos, Vincent M. Lynch

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

A series of novel, acyclic pyrrole-based anion receptors is described that bind nitrite and carboxylate anions with good selectivity in dichloroethane solution. These systems, which are based on pyridine 2,6-dicarboxamides, also bind cyanide anions weakly. Control systems, incorporating a benzene-1,3-dicarboxamide spacer or wherein the connectivity of the amide linkage is ``reversed'', either failed to act as effective anion receptors or displayed very different selectivities.
Original languageEnglish
Pages (from-to)646-654
Number of pages9
JournalNew Journal of Chemistry
Volume31
Issue number5
DOIs
Publication statusPublished - 2007

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Pyrroles
Anions
Negative ions
Ethylene Dichlorides
Cyanides
Nitrites
Benzene
Amides
Pyridine
Control systems

Cite this

Acyclic pyrrole-based anion receptors: design, synthesis, and anion-binding properties. / Sessler, Jonathan L.; Barkey, Natalie M.; Pantos, G. Dan; Lynch, Vincent M.

In: New Journal of Chemistry, Vol. 31, No. 5, 2007, p. 646-654.

Research output: Contribution to journalArticle

Sessler, Jonathan L. ; Barkey, Natalie M. ; Pantos, G. Dan ; Lynch, Vincent M. / Acyclic pyrrole-based anion receptors: design, synthesis, and anion-binding properties. In: New Journal of Chemistry. 2007 ; Vol. 31, No. 5. pp. 646-654.
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