Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

David J. Liptrot; Michael S. Hill; Mary F. Mahon

doi:10.1002/anie.201403208

Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

David J. Liptrot, Michael S. Hill, Mary F. Mahon

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Abstract

Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

Original language	English
Pages (from-to)	6224-6227
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	53
Issue number	24
Early online date	29 Apr 2014
DOIs	https://doi.org/10.1002/anie.201403208
Publication status	Published - 5 Jun 2014

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10.1002/anie.201403208

TEMPO_revised
This is the accepted version of the following article: Liptrot, DJ, Hill, MS & Mahon, MF 2014, 'Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes' Angewandte Chemie-International Edition, vol 53, no. 24, pp. 6224-6227., which has been published in final form at: http://dx.doi.org/10.1002/anie.201403208.
Accepted author manuscript, 623 KB

Cite this

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title = "Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes",

abstract = "Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes. ",

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AB - Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

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Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

Abstract

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Group 2: Elements of 21st Century Catalysis

Michael Hill

David Liptrot

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

Abstract

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Projects

Group 2: Elements of 21st Century Catalysis

Profiles

Michael Hill

David Liptrot

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

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