Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

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Abstract

Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.
Original languageEnglish
Pages (from-to)6224-6227
Number of pages4
JournalAngewandte Chemie-International Edition
Volume53
Issue number24
Early online date29 Apr 2014
DOIs
Publication statusPublished - 5 Jun 2014

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