Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

David J. Liptrot; Michael S. Hill; Mary F. Mahon

doi:10.1002/anie.201403208

Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

David J. Liptrot, Michael S. Hill, Mary F. Mahon

Research output: Contribution to journal › Article › peer-review

28 Citations (SciVal)

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Abstract

Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

Original language	English
Pages (from-to)	6224-6227
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	53
Issue number	24
Early online date	29 Apr 2014
DOIs	https://doi.org/10.1002/anie.201403208
Publication status	Published - 5 Jun 2014

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10.1002/anie.201403208

TEMPO_revised
This is the accepted version of the following article: Liptrot, DJ, Hill, MS & Mahon, MF 2014, 'Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes' Angewandte Chemie-International Edition, vol 53, no. 24, pp. 6224-6227., which has been published in final form at: http://dx.doi.org/10.1002/anie.201403208.
Accepted author manuscript, 623 KB

Group 2: Elements of 21st Century Catalysis
Hill, M. (PI)
Engineering and Physical Sciences Research Council
23/05/11 → 31/03/15
Project: Research council

Michael Hill
- M.S.Hillbath.acuk
Person: Research & Teaching, Affiliate staff
David Liptrot
- D.J.Liptrotbath.acuk
Person: Research & Teaching, Core staff, Affiliate staff

MC2- Nuclear Magnetic Resonance (NMR)
Material and Chemical Characterisation (MC2)
Facility/equipment: Technology type
MC2- X-ray diffraction (XRD)
Material and Chemical Characterisation (MC2)
Facility/equipment: Technology type

Cite this

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title = "Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes",

abstract = "Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes. ",

author = "Liptrot, {David J.} and Hill, {Michael S.} and Mahon, {Mary F.}",

year = "2014",

month = jun,

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doi = "10.1002/anie.201403208",

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volume = "53",

pages = "6224--6227",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Inc.",

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AU - Liptrot, David J.

AU - Hill, Michael S.

AU - Mahon, Mary F.

PY - 2014/6/5

Y1 - 2014/6/5

N2 - Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

AB - Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

U2 - 10.1002/anie.201403208

DO - 10.1002/anie.201403208

M3 - Article

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EP - 6227

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 24

ER -

Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

Abstract

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Projects

Group 2: Elements of 21st Century Catalysis

Profiles

Michael Hill

David Liptrot

Equipment

MC2- Nuclear Magnetic Resonance (NMR)

MC2- X-ray diffraction (XRD)

Cite this