Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes

Research output: Contribution to journalArticle

16 Citations (Scopus)
105 Downloads (Pure)

Abstract

Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.
Original languageEnglish
Pages (from-to)6224-6227
Number of pages4
JournalAngewandte Chemie-International Edition
Volume53
Issue number24
Early online date29 Apr 2014
DOIs
Publication statusPublished - 5 Jun 2014

Fingerprint

Silanes
Magnesium
Oxidation-Reduction
Hydrogen
Electrons

Cite this

@article{bf3ab3f0f191448d8b1b8293a776acf7,
title = "Accessing the single-electron manifold: Magnesium-mediated hydrogen release from silanes",
abstract = "Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.",
author = "Liptrot, {David J.} and Hill, {Michael S.} and Mahon, {Mary F.}",
year = "2014",
month = "6",
day = "5",
doi = "10.1002/anie.201403208",
language = "English",
volume = "53",
pages = "6224--6227",
journal = "Angewandte Chemie-International Edition",
issn = "1433-7851",
publisher = "WILEY-V C H VERLAG GMBH",
number = "24",

}

TY - JOUR

T1 - Accessing the single-electron manifold

T2 - Magnesium-mediated hydrogen release from silanes

AU - Liptrot, David J.

AU - Hill, Michael S.

AU - Mahon, Mary F.

PY - 2014/6/5

Y1 - 2014/6/5

N2 - Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

AB - Reactions of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO-mediated redox and Mg-O/Si-H metathesis processes.

U2 - 10.1002/anie.201403208

DO - 10.1002/anie.201403208

M3 - Article

VL - 53

SP - 6224

EP - 6227

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

SN - 1433-7851

IS - 24

ER -