Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

Monika Ali Khan; John P Lowe; Andrew L Johnson; A J W Stewart; Simon E Lewis

doi:10.1039/c0cc01169j

Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

Monika Ali Khan
, John P Lowe
, Andrew L Johnson
, A J W Stewart
, Simon E Lewis

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (SciVal)

422 Downloads (Pure)

Abstract

A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.

Original language	English
Pages (from-to)	215-217
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	1
Early online date	19 Aug 2010
DOIs	https://doi.org/10.1039/c0cc01169j
Publication status	Published - 7 Jan 2011

Access to Document

10.1039/c0cc01169j

Cite this

@article{ac3d54fd8d85426987ba4f8c05025459,

title = "Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation",

abstract = "A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.",

author = "\{Ali Khan\}, Monika and Lowe, \{John P\} and Johnson, \{Andrew L\} and Stewart, \{A J W\} and Lewis, \{Simon E\}",

year = "2011",

month = jan,

day = "7",

doi = "10.1039/c0cc01169j",

language = "English",

volume = "47",

pages = "215--217",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

AU - Ali Khan, Monika

AU - Lowe, John P

AU - Johnson, Andrew L

AU - Stewart, A J W

AU - Lewis, Simon E

PY - 2011/1/7

Y1 - 2011/1/7

N2 - A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.

AB - A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.

UR - https://www.scopus.com/pages/publications/78649819135

UR - http://dx.doi.org/10.1039/c0cc01169j

U2 - 10.1039/c0cc01169j

DO - 10.1039/c0cc01169j

M3 - Article

SN - 1359-7345

VL - 47

SP - 215

EP - 217

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

Abstract

Access to Document

Other files and links

Fingerprint

500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY

Cite this

Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

Abstract

Access to Document

Other files and links

Fingerprint

Projects

500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY

Cite this