Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

Monika Ali Khan; John P Lowe; Andrew L Johnson; A J W Stewart; Simon E Lewis

doi:10.1039/c0cc01169j

Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

Monika Ali Khan, John P Lowe, Andrew L Johnson, A J W Stewart, Simon E Lewis

Department of Chemistry

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Abstract

A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.

Original language	English
Pages (from-to)	215-217
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	1
Early online date	19 Aug 2010
DOIs	https://doi.org/10.1039/c0cc01169j
Publication status	Published - 7 Jan 2011

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abstract = "A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.",

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Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

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Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation

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500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY

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