Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters

Alan Ferguson, Julie McGregor, Euan K. Brechin, Lynne H. Thomas, Mark Murrie

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Abstract

The synthesis, structure and magnetic properties of [Fe14O4(OH)4(H2L)2(HL)4(piv)20] (1) and [Fe8Cu2O4(H2L)4(HL)2(OBz)12] (2) are reported (H3L = 2-amino-2-(hydroxymethyl)propane-1,3-diol): both complexes have unique core structures and display non-zero spin ground states.
Original languageEnglish
Pages (from-to)9395-9397
Number of pages3
JournalDalton Transactions
Issue number43
Early online date14 Sep 2009
DOIs
Publication statusPublished - 2009

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Ferguson, A., McGregor, J., Brechin, E. K., Thomas, L. H., & Murrie, M. (2009). Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters. Dalton Transactions , (43), 9395-9397. https://doi.org/10.1039/b913102g