Accelerating innovations in C[sbnd]H activation/functionalization through intricately designed magnetic nanomaterials: From genesis to applicability in liquid/regio/photo catalysis

Sriparna Dutta, Prashant Kumar, Sneha Yadav, Ruchi Dubey Sharma, Parimala Shivaprasad, Karani S. Vimaleswaran, Anju Srivastava, Rakesh K. Sharma

Research output: Contribution to journalReview articlepeer-review

5 Citations (SciVal)

Abstract

Selective functionalization of highly inert and ubiquitous C[sbnd]H bonds that would provide a ready access to synthetically valuable motifs has perplexed the chemists since long. Also, environmental benignity and economic viability have been the prime factors driving tremendous interest in C[sbnd]H functionalization. This has led to many inspiring discoveries infuriating the development of potent catalytic systems that enable the facile replacement of the C[sbnd]H bonds with conventional functional groups, allowing the construction of C-C, C-N, C-O, C-S, C-B and C-halogen bonds at both sp2 as well as sp3 centres. In fact, catalytic C[sbnd]H functionalization strategies integrating the benefits of magnetic recovery have emerged as sustainable gateway for affording a diverse array of transformations. This review sheds light on the remarkable advancements witnessed in this area as a consequence of integrating the inherent magnetism of catalysts with the cutting-edge direct C[sbnd]H functionalization strategy. Also, the promising future perspectives comprehensively covered in this review is anticipated to motivate the academic and industrial researchers, arousing their creativity for designing competent sustainable strategies to generate a plethora of pharmaceutically active molecules.

Original languageEnglish
Article number106615
JournalCatalysis Communications
Volume175
Early online date20 Jan 2023
DOIs
Publication statusPublished - 28 Feb 2023

Bibliographical note

Funding Information:
The authors would like to thank British Council for providing grant for INDO-UK Collaborative workshop and this research output is an outcome of the same. One of the authors would also like to express gratitude to SERB for providing fund to Dr. Prashant Kumar under the scheme of Teacher Associateship for Research Excellence (TARE) (File number TAR/2021/000201).

Data availability
Data will be made available on request.

Keywords

  • C[sbnd]H functionalization
  • Heterocycles
  • Magnetic nanocatalysts
  • Magnetic retrievability
  • Sustainable synthesis

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Process Chemistry and Technology

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