A unique li12-aggregate containing both -NLi2 and -CHLi ∼ NLi units

Sarah C. Ball, James Cobb, Robert P. Davies, Paul R. Raithby, Gregory P. Shields, Ronald Snaith

Research output: Contribution to journalArticlepeer-review

4 Citations (SciVal)

Abstract

Dilithiation of 2-methylpyridine followed by PhCN insertion affords the complex {[C5H4N·CHC(Ph)N]2-·2Li+}6·(THF)4, 5. The crystal structure of 5 reveals an unusual Li12 aggregate containing four types of Li+ cation and two types of dianionic ligand which bond to the metal centres via exclusively N-Li interactions or via combinations of C-Li and N-Li coordinations.

Original languageEnglish
Pages (from-to)241-245
Number of pages5
JournalJournal of Organometallic Chemistry
Volume534
Issue number1-2
DOIs
Publication statusPublished - 28 Apr 1997

Bibliographical note

Funding Information:
We thank the EPSRC (S.C.B., R.P.D., G.P.S.), the CCDC (G.P.S.), the Associated Octel Co. Ltd. (S.C.B., R.P.D.) and the Royal Society (low-temperature X-ray diffraction apparatus, P.R.R.) for financial support. We are also much indebted to Dr. Basil Wakefield (University of Salford) for many useful comments and suggestions, particularly regarding the "organic chemist's point of view".

Keywords

  • Dilithiated molecules
  • Imide
  • Lithium
  • Pyridine
  • Reaction mechanisms
  • X-ray structure

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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