A Triosmium Cluster Complex with a Carbene Ligand in an Unusual Coordination Mode

Andrew J. Edwards; Mark A. Gallop; Brian F.G. Johnson; Jochem U. Köhler; Jack Lewis; Paul R. Raithby

doi:10.1002/anie.199410931

A Triosmium Cluster Complex with a Carbene Ligand in an Unusual Coordination Mode

Andrew J. Edwards, Mark A. Gallop, Brian F.G. Johnson, Jochem U. Köhler, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os₃ framework. (Figure Presented.)

Original language	English
Pages (from-to)	1093-1094
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	10
DOIs	https://doi.org/10.1002/anie.199410931
Publication status	Published - 6 Jun 1994

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.199410931

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abstract = "The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os3 framework. (Figure Presented.)",

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AU - Lewis, Jack

AU - Raithby, Paul R.

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Y1 - 1994/6/6

N2 - The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os3 framework. (Figure Presented.)

AB - The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os3 framework. (Figure Presented.)

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A Triosmium Cluster Complex with a Carbene Ligand in an Unusual Coordination Mode

Abstract

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