TY - JOUR
T1 - A stereochemical investigation of the cyclisation of D-glucose-6[(R)-16O,17O,18O]phosphate and adenosine-5′[(R)-16O,17O,18O]phosphate
AU - Jarvest, Richard L.
AU - Lowe, Gordon
AU - Potter, Barry V. L.
PY - 1980
Y1 - 1980
N2 - D-Glucose-6[(R)-16O,17O,18O] phosphate and adenosine-5′[(R)-16O,17O,18O] phosphate were synthesised and converted (by treatment with diphenyl phosphorochloridate, followed by potassium t-butoxide) into the cyclic 4,6-phosphate and 3′5′-phosphate diesters respectively with retention of configuration at phosphorus; the absolute configuration of D-glucose-6[16O,17O,18O]phosphate and adenosine-5′[16O,17O,18O]phosphate of unknown chirality at phosphorus can now be determined by 31P n.m.r. spectroscopy
AB - D-Glucose-6[(R)-16O,17O,18O] phosphate and adenosine-5′[(R)-16O,17O,18O] phosphate were synthesised and converted (by treatment with diphenyl phosphorochloridate, followed by potassium t-butoxide) into the cyclic 4,6-phosphate and 3′5′-phosphate diesters respectively with retention of configuration at phosphorus; the absolute configuration of D-glucose-6[16O,17O,18O]phosphate and adenosine-5′[16O,17O,18O]phosphate of unknown chirality at phosphorus can now be determined by 31P n.m.r. spectroscopy
UR - http://dx.doi.org/10.1039/C39800001142
U2 - 10.1039/C39800001142
DO - 10.1039/C39800001142
M3 - Article
SN - 0022-4936
VL - 1980
SP - 1142
EP - 1145
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 23
ER -