A stable methyl phosphane oxide/lithium amide complex: A structural and MO calculational investigation of the mechanism of proton abstraction by alkali metal reagents

David R. Armstrong, Matthew G. Davidson, Robert P. Davies, Helen J. Mitchell, Rachel M. Oakley, Paul R. Raithby, Ronald Snaith, Stuart Warren

Research output: Contribution to journalArticlepeer-review

Abstract

The initiation step in a deprotonation of CH-acidic compounds could be the formation of a complex between the organic precursor and the metalation reagent. This is the conclusion drawn from the reaction of Ph2P(O)CH3 with (Me3Si)2NLi, which yielded a stable dimeric adduct [(Me3Si)2NLi·OP(CH3)Ph2]2 with a central Li2N2 ring. MO calculations on the model system H2LiNLi·OP(CH3)2 support these experimental findings.
Original languageEnglish
Pages (from-to)1942-1944
Number of pages3
JournalAngewandte Chemie (International Edition in English)
Volume35
Issue number17
DOIs
Publication statusPublished - 20 Sep 1996

Keywords

  • ab initio calculations
  • Amides
  • Lithium compounds
  • Phosphorus compounds
  • Solid-state structures

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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