A Stable Calcium Alumanyl

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Abstract

A seven‐membered N,N′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Mg−Ca bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.
Original languageEnglish
JournalAngewandte Chemie-International Edition
Early online date12 Dec 2019
DOIs
Publication statusE-pub ahead of print - 12 Dec 2019

Cite this

@article{c66fd3629303437f98ea044441fd6bce,
title = "A Stable Calcium Alumanyl",
abstract = "A seven‐membered N,N′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Mg−Ca bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.",
author = "Michael Hill and Ryan Schwamm and Martyn Coles and Mary Mahon and Claire McMullin and Nasir Rajabi and Andrew Wilson",
year = "2019",
month = "12",
day = "12",
doi = "10.1002/anie.201914986",
language = "English",
journal = "Angewandte Chemie-International Edition",
issn = "1433-7851",
publisher = "WILEY-V C H VERLAG GMBH",

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T1 - A Stable Calcium Alumanyl

AU - Hill, Michael

AU - Schwamm, Ryan

AU - Coles, Martyn

AU - Mahon, Mary

AU - McMullin, Claire

AU - Rajabi, Nasir

AU - Wilson, Andrew

PY - 2019/12/12

Y1 - 2019/12/12

N2 - A seven‐membered N,N′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Mg−Ca bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.

AB - A seven‐membered N,N′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Mg−Ca bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.

U2 - 10.1002/anie.201914986

DO - 10.1002/anie.201914986

M3 - Article

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

SN - 1433-7851

ER -