A Stable Calcium Alumanyl

Michael Hill; Ryan Schwamm; Martyn  Coles; Mary Mahon; Claire McMullin; Nasir Rajabi; Andrew Wilson

doi:10.1002/anie.201914986

A Stable Calcium Alumanyl

Michael Hill, Ryan Schwamm, Martyn Coles, Mary Mahon, Claire McMullin, Nasir Rajabi, Andrew Wilson

Victoria University of Wellington

Research output: Contribution to journal › Article › peer-review

123 Citations (SciVal)

88 Downloads (Pure)

Abstract

A seven-membered N,N′-heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Ca−Al bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.

Original language	English
Pages (from-to)	3928-3932
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	59
Issue number	10
Early online date	12 Dec 2019
DOIs	https://doi.org/10.1002/anie.201914986
Publication status	Published - 2 Mar 2020

Bibliographical note

Keywords

alumanyl
calcium
density functional theory
magnesium
potassium

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.201914986

Ca_alumanyl_templated_manuscript_for_production.pdf
This is the peer reviewed version of the following article: Hill, M..S., Schwamm, R., Coles, M., Mahon, M., McMullin, C., Rajabi, N. and Wilson, A. (2020), A Stable Calcium Aluminyl . Angew. Chem. Int. Ed.. Accepted Author Manuscript., which has been published in final form at https://doi.org/10.1002/anie.201914986. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Accepted author manuscript, 1.71 MB

Cite this

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AU - Wilson, Andrew

PY - 2020/3/2

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A Stable Calcium Alumanyl

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

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Fingerprint

Nucleophilic alkaline earth boryls: from conception and theory to application

Michael Hill

Balena High Performance Computing (HPC) System

Cite this

A Stable Calcium Alumanyl

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Projects

Nucleophilic alkaline earth boryls: from conception and theory to application

Profiles

Michael Hill

Equipment

Balena High Performance Computing (HPC) System

Cite this