A Stable Calcium Alumanyl

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Abstract

A seven-membered N,N′-heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Ca−Al bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.

Original languageEnglish
Pages (from-to)3928-3932
Number of pages5
JournalAngewandte Chemie-International Edition
Volume59
Issue number10
Early online date12 Dec 2019
DOIs
Publication statusPublished - 2 Mar 2020

Keywords

  • alumanyl
  • calcium
  • density functional theory
  • magnesium
  • potassium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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