Abstract
A membrane ozonation contactor was built to investigate ozonation using tubular membranes and inform computational fluid dynamics (CFD) studies. Non-porous tubular polydimethylsiloxane (PDMS) membranes of 1.0–3.2 mm inner diameter were tested at ozone gas concentrations of 110–200 g/m3 and liquid side velocities of 0.002–0.226 m/s. The dissolved ozone concentration could be adjusted to up to 14 mg O3/L and increased with decreasing membrane diameter and liquid side velocity. Experimental mass transfer coefficients and molar fluxes of ozone were 2.4 × 10−6 m/s and 1.1 × 10−5 mol/(m2 s), respectively, for the smallest membrane. CFD modelling could predict the final ozone concentrations but slightly overestimated mass transfer coefficients and molar fluxes of ozone. Model contaminant degradation experiments and UV light absorption measurements of ozonated water samples in both ozone (O3) and peroxone (H2O2/O3) reaction systems in pure water, river water, wastewater effluent, and solutions containing humic acid show that the contactor system can be used to generate information on the reactivity of ozone with different water matrices. Combining simple membrane contactors with CFD allows for prediction of ozonation performance under a variety of conditions, leading to improved bubble-less ozone systems for water treatment.
Original language | English |
---|---|
Article number | 1416 |
Number of pages | 14 |
Journal | Water |
Volume | 10 |
Issue number | 10 |
DOIs | |
Publication status | Published - 10 Oct 2018 |
Fingerprint
Dive into the research topics of 'A Single Tube Contactor for Testing Membrane Ozonation'. Together they form a unique fingerprint.Profiles
-
John Chew
- Department of Chemical Engineering - Head of Department
- Water Innovation and Research Centre (WIRC)
- Centre for Digital, Manufacturing & Design (dMaDe)
- IAAPS: Propulsion and Mobility
Person: Research & Teaching, Core staff, Affiliate staff
-
Davide Mattia
- Department of Chemical Engineering - Professor
- Institute of Sustainability and Climate Change
- Centre for Integrated Materials, Processes & Structures (IMPS)
Person: Research & Teaching, Core staff, Affiliate staff
-
Jannis Wenk
- Department of Chemical Engineering - Senior Lecturer
- Water Innovation and Research Centre (WIRC)
- Centre for Sustainable and Circular Technologies (CSCT)
- Centre for Digital, Manufacturing & Design (dMaDe)
Person: Research & Teaching, Core staff