A single-source precursor route to antimony sulpho-iodide

G Kociok-Kohn; K C Molloy; J Rodriguez-Castro

doi:10.1016/j.inoche.2008.02.027

A single-source precursor route to antimony sulpho-iodide

G Kociok-Kohn, K C Molloy, J Rodriguez-Castro

Department of Chemistry

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9 Citations (SciVal)

Abstract

Antimony sulpho-iodide has been synthesised from the single-source precursors S(CH2CH2S)(2)SbI or (CH2S)(2)SbI by a novel intramolecular decomposition pathway which involves elimination of 1,4-dithiane whilst preserving the weak Sb-I bond. Both precursors have been characterised by X-ray crystallography. (C) 2008 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	599-603
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2008.02.027
Publication status	Published - 2008

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ID number: ISI:000257039700002

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10.1016/j.inoche.2008.02.027

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AB - Antimony sulpho-iodide has been synthesised from the single-source precursors S(CH2CH2S)(2)SbI or (CH2S)(2)SbI by a novel intramolecular decomposition pathway which involves elimination of 1,4-dithiane whilst preserving the weak Sb-I bond. Both precursors have been characterised by X-ray crystallography. (C) 2008 Elsevier B.V. All rights reserved.

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A single-source precursor route to antimony sulpho-iodide

Abstract

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