A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe2)2}K·pmdeta]2 and [{CyNAs(NMe2)2K}2](∞)

Michael A. Beswick; Alan Bashall; Alexander D. Hopkins; Sara J. Kidd; Yvonne G. Lawson; Mary McPartlin; Paul R. Raithby; Alexander Rothenberger; Dietmar Stalke; Dominic S. Wright

doi:10.1039/a901222b

A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe₂)₂}K·pmdeta]₂ and [{CyNAs(NMe₂)₂K}₂](∞)

Michael A. Beswick
, Alan Bashall
, Alexander D. Hopkins
, Sara J. Kidd
, Yvonne G. Lawson
, Mary McPartlin
, Paul R. Raithby
, Alexander Rothenberger
, Dietmar Stalke
, Dominic S. Wright

University of Cambridge
London Metropolitan University
Universitât Würzburg

Research output: Contribution to journal › Article › peer-review

7 Citations (SciVal)

Abstract

The syntheses of [Bu(t)PAs(NMe₂)₂K·pmedta]₂ 1 and [{CyNAs(NMe₂)₂K}₂](∞) 2 from the reactions of [As(NMe₂)₃] with Bu(t)PH₂ and CyNH₂, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

Original language	English
Pages (from-to)	739-740
Number of pages	2
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/a901222b
Publication status	Published - 21 Apr 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a901222b

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Beswick, M. A., Bashall, A., Hopkins, A. D., Kidd, S. J., Lawson, Y. G., McPartlin, M., Raithby, P. R., Rothenberger, A., Stalke, D., & Wright, D. S. (1999). A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe₂)₂}K·pmdeta]₂ and [{CyNAs(NMe₂)₂K}₂](∞). Chemical Communications, (8), 739-740. https://doi.org/10.1039/a901222b

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title = "A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [\{Bu(t)PAs(NMe2)2\}K·pmdeta]2 and [\{CyNAs(NMe2)2K\}2](∞)",

abstract = "The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [\{CyNAs(NMe2)2K\}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.",

author = "Beswick, \{Michael A.\} and Alan Bashall and Hopkins, \{Alexander D.\} and Kidd, \{Sara J.\} and Lawson, \{Yvonne G.\} and Mary McPartlin and Raithby, \{Paul R.\} and Alexander Rothenberger and Dietmar Stalke and Wright, \{Dominic S.\}",

year = "1999",

month = apr,

day = "21",

doi = "10.1039/a901222b",

language = "English",

pages = "739--740",

journal = "Chemical Communications",

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T1 - A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe2)2}K·pmdeta]2 and [{CyNAs(NMe2)2K}2](∞)

AU - Beswick, Michael A.

AU - Bashall, Alan

AU - Hopkins, Alexander D.

AU - Kidd, Sara J.

AU - Lawson, Yvonne G.

AU - McPartlin, Mary

AU - Raithby, Paul R.

AU - Rothenberger, Alexander

AU - Stalke, Dietmar

AU - Wright, Dominic S.

PY - 1999/4/21

Y1 - 1999/4/21

N2 - The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [{CyNAs(NMe2)2K}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

AB - The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [{CyNAs(NMe2)2K}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

UR - https://www.scopus.com/pages/publications/0033591020

U2 - 10.1039/a901222b

DO - 10.1039/a901222b

M3 - Article

AN - SCOPUS:0033591020

SN - 1359-7345

SP - 739

EP - 740

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe₂)₂}K·pmdeta]₂ and [{CyNAs(NMe₂)₂K}₂](∞)

Abstract

ASJC Scopus subject areas

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