A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe2)2}K·pmdeta]2 and [{CyNAs(NMe2)2K}2](∞)

Michael A. Beswick, Alan Bashall, Alexander D. Hopkins, Sara J. Kidd, Yvonne G. Lawson, Mary McPartlin, Paul R. Raithby, Alexander Rothenberger, Dietmar Stalke, Dominic S. Wright

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [{CyNAs(NMe2)2K}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

Original languageEnglish
Pages (from-to)739-740
Number of pages2
JournalChemical Communications
Issue number8
DOIs
Publication statusPublished - 21 Apr 1999

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe<sub>2</sub>)<sub>2</sub>}K·pmdeta]<sub>2</sub> and [{CyNAs(NMe<sub>2</sub>)<sub>2</sub>K}<sub>2</sub>](∞)'. Together they form a unique fingerprint.

Cite this