A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe2)2}K·pmdeta]2 and [{CyNAs(NMe2)2K}2](∞)

Michael A. Beswick; Alan Bashall; Alexander D. Hopkins; Sara J. Kidd; Yvonne G. Lawson; Mary McPartlin; Paul R. Raithby; Alexander Rothenberger; Dietmar Stalke; Dominic S. Wright

doi:10.1039/a901222b

A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe₂)₂}K·pmdeta]₂ and [{CyNAs(NMe₂)₂K}₂](∞)

Michael A. Beswick, Alan Bashall, Alexander D. Hopkins, Sara J. Kidd, Yvonne G. Lawson, Mary McPartlin, Paul R. Raithby, Alexander Rothenberger, Dietmar Stalke, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

7 Citations (SciVal)

Abstract

The syntheses of [Bu(t)PAs(NMe₂)₂K·pmedta]₂ 1 and [{CyNAs(NMe₂)₂K}₂](∞) 2 from the reactions of [As(NMe₂)₃] with Bu(t)PH₂ and CyNH₂, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

Original language	English
Pages (from-to)	739-740
Number of pages	2
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/a901222b
Publication status	Published - 21 Apr 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a901222b

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Beswick, M. A., Bashall, A., Hopkins, A. D., Kidd, S. J., Lawson, Y. G., McPartlin, M., Raithby, P. R., Rothenberger, A., Stalke, D., & Wright, D. S. (1999). A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe₂)₂}K·pmdeta]₂ and [{CyNAs(NMe₂)₂K}₂](∞). Chemical Communications, (8), 739-740. https://doi.org/10.1039/a901222b

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abstract = "The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [{CyNAs(NMe2)2K}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.",

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AU - Beswick, Michael A.

AU - Bashall, Alan

AU - Hopkins, Alexander D.

AU - Kidd, Sara J.

AU - Lawson, Yvonne G.

AU - McPartlin, Mary

AU - Raithby, Paul R.

AU - Rothenberger, Alexander

AU - Stalke, Dietmar

AU - Wright, Dominic S.

PY - 1999/4/21

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AB - The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [{CyNAs(NMe2)2K}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

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ER -

A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe₂)₂}K·pmdeta]₂ and [{CyNAs(NMe₂)₂K}₂](∞)

Abstract

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