A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru5C(CO)15.MeCN

Brian F.G. Johnson; Jack Lewis; Jack Nicola Nicholls; Ian A. Oxton; Paul R. Raithby; Maria J. Rosales

doi:10.1039/C39820000289

A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru₅C(CO)₁₅.MeCN

Brian F.G. Johnson, Jack Lewis, Jack Nicola Nicholls, Ian A. Oxton, Paul R. Raithby, Maria J. Rosales

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster complex Ru₅C(CO)₁₅ reacts with acetonitrile to produce the adduct Ru₅C(CO)₁₅.MeCN with a concomitant rearrangement of the Ru₅C Unit from square-pyramidal to arachno-pentagonal bipyramidal geometry.

Original language	English
Pages (from-to)	289-290
Number of pages	2
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39820000289
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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Johnson, B. F. G., Lewis, J., Nicholls, J. N., Oxton, I. A., Raithby, P. R., & Rosales, M. J. (1982). A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru₅C(CO)₁₅.MeCN. Journal of the Chemical Society - Series Chemical Communications, (5), 289-290. https://doi.org/10.1039/C39820000289

A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru₅C(CO)₁₅.MeCN. / Johnson, Brian F.G.; Lewis, Jack; Nicholls, Jack Nicola et al.
In: Journal of the Chemical Society - Series Chemical Communications, No. 5, 1982, p. 289-290.

Research output: Contribution to journal › Article › peer-review

Johnson, BFG, Lewis, J, Nicholls, JN, Oxton, IA, Raithby, PR & Rosales, MJ 1982, 'A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru₅C(CO)₁₅.MeCN', Journal of the Chemical Society - Series Chemical Communications, no. 5, pp. 289-290. https://doi.org/10.1039/C39820000289

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title = "A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru5C(CO)15.MeCN",

abstract = "The cluster complex Ru5C(CO)15 reacts with acetonitrile to produce the adduct Ru5C(CO)15.MeCN with a concomitant rearrangement of the Ru5C Unit from square-pyramidal to arachno-pentagonal bipyramidal geometry.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Nicholls, \{Jack Nicola\} and Oxton, \{Ian A.\} and Raithby, \{Paul R.\} and Rosales, \{Maria J.\}",

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A reversible skeletal rearrangement in a metal cluster complex; the formation and characterisation by I.R. spectroscopy and x-ray crystallography of Ru₅C(CO)₁₅.MeCN

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